H3PW12O40 catalyzed liquid phase nitration of aromatics - a green process without using H2SO4

被引：0
|
作者：
Lu, Lianhai [1 ,2 ]
Xin, Junna [1 ]
Woo, Chang-Soo [2 ]
Cai, Tianxi [1 ]
Lee, Ho-In [2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Seoul Natl Univ, Sch Chem & Biol Engn, Energy Res Ctr Convers & Storage, Seoul 151, South Korea
来源：
NEW DEVELOPMENT AND APPLICATION IN CHEMICAL REACTION ENGINEERING, 4TH ASIA-PACIFIC CHEMICAL REACTION ENGINEERING SYMPOSIUM (APCRE 05) | 2006年 / 159卷
关键词：
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
H3PW12O40 with Keggin structure showed excellent activity for liquid phase nitration of various aromatic compounds, suggesting the possibility of a green nitration process by simply replacing H2SO4 in current nitration unit. The H3PW12O40 could be recycled to use with constant activity. Effects of various reaction parameters were investigated extensively.
引用
收藏
页码：353 / 356
页数：4
相关论文
共 50 条
  • [1] DEHYDRATION OF ALCOHOLS IN THE PSEUDO-LIQUID PHASE OF H3PW12O40
    MISONO, M
    OKUHARA, T
    KANDA, Y
    TAKAHASHI, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 424 - INOR
  • [2] H3PW12O40 catalyzed efficient synthesis of 4-substituted coumarins
    Raju, B. China
    Babu, T. Hari
    Rao, J. Madhusudana
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2009, 48 (01): : 120 - 123
  • [3] CONDENSATION OF ACETONE CATALYZED BY A HETEROPOLY ACID, H3PW12O40
    KHANKHASAEVA, ST
    KULIKOV, SM
    KOZHEVNIKOV, IV
    KINETICS AND CATALYSIS, 1990, 31 (01) : 188 - 191
  • [4] Cyclization of (+)-citronellal to (-)-isopulegol catalyzed by H3PW12O40/SiO2
    da Silva, KA
    Robles-Dutenhefner, PA
    Sousa, EMB
    Kozhevnikova, EF
    Kozhevnikov, IV
    Gusevskaya, EV
    CATALYSIS COMMUNICATIONS, 2004, 5 (08) : 425 - 429
  • [5] Investigation on the esterification of fatty acids catalyzed by the H3PW12O40 heteropolyacid
    Cardoso, Abiney L.
    Augusti, Rodinei
    Da Silva, Marcio J.
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2008, 85 (06) : 555 - 560
  • [6] H3PW12O40 catalyzed synthesis of benzoxazine and quinazoline in aqueous media
    Tajbakhsh, Mahmood
    Hosseinzadeh, Rahman
    Rezaee, Parizad
    Tajbakhsh, Mahgol
    CHINESE JOURNAL OF CATALYSIS, 2014, 35 (01) : 58 - 65
  • [7] POLYMERIZATION OF TETRAHYDROFURAN CATALYZED BY THE H3PW12O40 HETEROPOLYACID IN THE PRESENCE OF ALCOHOLS
    MAKSIMOV, GM
    GOLOVIN, AV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1994, 36 (03): : 499 - 502
  • [8] Selective oxidation of cyclopentene with H2O2 by using H3PW12O40 and TBAB as a phase transfer catalyst
    Luo, Yaling
    Liu, Changjun
    Yue, Hairong
    Tang, Siyang
    Zhu, Yingming
    Liang, Bin
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2019, 27 (08) : 1851 - 1856
  • [9] EVIDENCE FOR PSEUDO-LIQUID PHASE IN THE DEHYDRATION OF ISOPROPANOL OVER H3PW12O40
    OKUHARA, T
    HASHIMOTO, T
    MISONO, M
    YONEDA, Y
    NIIYAMA, H
    SAITO, Y
    ECHIGOYA, E
    CHEMISTRY LETTERS, 1983, (04) : 573 - 576
  • [10] Selective oxidation of cyclopentene with H2O2 by using H3PW12O40 and TBAB as a phase transfer catalyst
    Yaling Luo
    Changjun Liu
    Hairong Yue
    Siyang Tang
    Yingming Zhu
    Bin Liang
    ChineseJournalofChemicalEngineering, 2019, 27 (08) : 1851 - 1856
12345