A Ce-Cu-Ti oxide catalyst for the selective catalytic reduction of NO with NH3

被引:136
作者
Gao, Xiang [1 ]
Du, Xue-sen [1 ]
Cui, Li-wen [1 ]
Fu, Yin-cheng [1 ]
Luo, Zhong-yang [1 ]
Cen, Ke-fa [1 ]
机构
[1] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Selective catalytic reduction; Ceria oxide; Copper oxide; Anatase; NH3; SO2; resistance; CERIUM; SO2; AMMONIA; O-2;
D O I
10.1016/j.catcom.2010.09.029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A Ce-Cu-Ti complex oxide catalyst for the selective catalytic reduction of NO with NH3 was prepared by coprecipitation method XRD and H-2-TPR reveal that the strong interaction between Ce and Cu results in the production of a new active oxygen species with high reducibility at low temperatures Compared with Ce-Ti oxide catalyst the Ce-Cu-Ti oxide catalyst produces better performance at the temperatures lower than 350 C and higher SO2-resistent ability H2O will reduce the SCR activity of Ce-Cu-Ti catalyst at low temperatures while promoting the catalyst performance at temperatures more than 350 C (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:255 / 258
页数:4
相关论文
共 23 条
[1]   DRIFT study of the interaction of NO and O2 with the surface of Ce0.62Zr0.38O2 as deNOx catalyst [J].
Adamowska, Malgorzata ;
Krzton, Andrzej ;
Najbar, Mieczyslawa ;
Da Costa, Patrick ;
Djega-Mariadassou, Gerald .
CATALYSIS TODAY, 2008, 137 (2-4) :288-291
[2]   High Oxygen Storage Capacity and High Rates of CO Oxidation and NO Reduction Catalytic Properties of Ce1-xSnxO2 and Ce0.78Sn0.2Pd0.02O2-δ [J].
Baidya, Tinku ;
Gupta, Asha ;
Deshpandey, Paraag A. ;
Madras, Giridhar ;
Hegde, M. S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (10) :4059-4068
[3]   Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts:: A review [J].
Busca, G ;
Lietti, L ;
Ramis, G ;
Berti, F .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 18 (1-2) :1-36
[4]   Screening of doped MnOx-CeO2 catalysts for low-templerature NO-SCR [J].
Casapu, Maria ;
Kroecher, Oliver ;
Elsener, Martin .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 88 (3-4) :413-419
[5]   Lanthanide doped V2O5/Al2O3 catalysts:: Structure-activity relationship in the SCR of NOx [J].
Centeno, MA ;
Malet, P ;
Carrizosa, I ;
Odriozola, JA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (14) :3310-3319
[6]   Promotional Effect of Ce-doped V2O5-WO3/TiO2 with Low Vanadium Loadings for Selective Catalytic Reduction of NOx by NH3 [J].
Chen, Liang ;
Li, Junhua ;
Ge, Maofa .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (50) :21177-21184
[7]   Role of cerium in promoting the stability of CuHM catalyst against HCl to reduce NO with NH3 [J].
Choung, Jin Woo ;
Nam, In-Sik .
APPLIED CATALYSIS A-GENERAL, 2006, 312 :165-174
[8]   Oxidation of SO2 over supported metal oxide catalysts [J].
Dunn, JP ;
Stenger, HG ;
Wachs, IE .
JOURNAL OF CATALYSIS, 1999, 181 (02) :233-243
[9]   Selective reduction of NO by NH3 over manganese-cerium mixed oxides:: Relation between adsorption, redox and catalytic behavior [J].
Eigenmann, F ;
Maciejewski, M ;
Baiker, A .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 62 (3-4) :311-318
[10]   Preparation and characterization of CeO2/TiO2 catalysts for selective catalytic reduction of NO with NH3 [J].
Gao, Xiang ;
Jiang, Ye ;
Fu, Yincheng ;
Zhong, Yi ;
Luo, Zhongyang ;
Cen, Kefa .
CATALYSIS COMMUNICATIONS, 2010, 11 (05) :465-469