Bis{2,2′-[(2-aminoethyl)azanediyl]diethanaminium} di-μ-sulfido-bis(disulfidogermanate)

被引：3

作者：

Xu, Chao ^{[1
]}

Zhang, Jing-Jing ^{[1
]}

Duan, Taike ^{[1
]}

Chen, Qun ^{[2
]}

Zhang, Qian-Feng ^{[1
,2
]}

机构：

[1] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Anhui 243002, Peoples R China

[2] Changzhou Univ, Sch Petrochem Engn, Dept Appl Chem, Jiangsu 213164, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

data-to-parameter ratio = 18.6; mean σ(C-C) = 0.006 Å; R factor = 0.042; single-crystal X-ray study; T = 296 K; wR factor = 0.111;

D O I：

10.1107/S160053681200092X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, (C6H20N4)2[Ge2S6], the dimeric [Ge2S6](4-) anion is formed by two edge-sharing GeS4 tetrahedral units. The average terminal and bridging Ge-S bond lengths are 2.158 (14) and 2.276 (6) angstrom, respectively. The anions and the diprotonated ammonium cations are organized into a three-dimensional network by N-H center dot center dot center dot S and N-H center dot center dot center dot N hydrogen bonds.

引用

页码：M154 / U707

页数：9

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