Sticky superhydrophobic filter paper developed by dip-coating of fluorinated waterborne epoxy emulsion

被引：64

作者：

Huang, Xiangxuan ^{[1
]}

Wen, Xiufang ^{[1
]}

Cheng, Jiang ^{[1
]}

Yang, Zhuoru ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2012年 / 258卷 / 22期

关键词：

Epoxy resin; Superhydrophobic; Superoleophilic; Sticky; Cellulose; Impregnating agent; SILICA NANOPARTICLES; SURFACES; FABRICATION; TEXTILES; POLYMER; FILMS; WETTABILITY; OIL;

D O I：

10.1016/j.apsusc.2012.05.083

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A superhydrophobic and superoleophilic coating for oil filter paper was synthesized based on waterborne bisphenol-A novolac epoxy emulsion. The benzoic acid (BA) and maleic anhydride (MA) were used as modification agents to give the epoxy resin hydrophilic groups (carboxyl) and C=C double bonds. And the fluorinated waterborne epoxy emulsion was prepared by free radical solution polymerization of dodecafluoroheptyl methacrylate (DFMA) monomer. The covalent bound low free energy fluorinated chains in the monomer reduce the surface energy of solidification polymers sufficiently to give rise to superhydrophobic behavior while conserving superoleophilicity. Surfaces prepared show a sticky property, which exhibits a static water contact angle of 152 degrees for a 5 mu L droplet that does not slid off even when the sample is held upside down. This synthetic emulsion is simple and convenient as impregnating agent for filter paper, which can be considered as a suitable candidate for various substrates such as cotton textiles, E-glass and artificial fiber, and so on. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：8739 / 8746

页数：8

共 45 条

[1] Fabrication of "roll-off" and "sticky" superhydrophobic cellulose surfaces via plasma processing [J].

Balu, Balarnurali ;

Breedveld, Victor ;

Hess, Dennis W. .

LANGMUIR, 2008, 24 (09) :4785-4790

[2] Structure and oil repellency - Textiles with liquid repellency to hexane [J].

Brewer, Stuart A. ;

Willis, Colin R. .

APPLIED SURFACE SCIENCE, 2008, 254 (20) :6450-6454

[3] Wettability of porous surfaces. [J].

Cassie, ABD ;

Baxter, S .

TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550

[4] A facile dip-coating process for preparing highly durable superhydrophobic surface with multi-scale structures on paint films [J].

Cui, Zhe ;

Yin, Long ;

Wang, Qingjun ;

Ding, Jianfu ;

Chen, Qingmin .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 337 (02) :531-537

[5] Highly hydrophobic biopolymers prepared by the surface pentafluorobenzoylation of cellulose substrates [J].

Cunha, Ana G. ;

Freire, Carmen S. R. ;

Silvestre, Armando J. D. ;

Neto, Carlos Pascoal ;

Gandini, Alessandro ;

Orblin, Elina ;

Fardim, Pedro .

BIOMACROMOLECULES, 2007, 8 (04) :1347-1352

[6] Electrodeposited polymer films with both superhydrophobicity and superoleophilicity [J].

Darmanin, Thierry ;

Nicolas, Mael ;

Guittard, Frederic .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (29) :4322-4326

[7] Nanotexturing of polystyrene surface in fluorocarbon plasmas: From sticky to slippery superhydrophobicity [J].

Di Mundo, Rosa ;

Palumbo, Fabio ;

d'Agostino, Riccardo .

LANGMUIR, 2008, 24 (09) :5044-5051

[8] Biomimicry in textiles: past, present and potential. An overview [J].

Eadie, Leslie ;

Ghosh, Tushar K. .

JOURNAL OF THE ROYAL SOCIETY INTERFACE, 2011, 8 (59) :761-775

[9] A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water [J].

Feng, L ;

Zhang, ZY ;

Mai, ZH ;

Ma, YM ;

Liu, BQ ;

Jiang, L ;

Zhu, DB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (15) :2012-2014

[10]

Frone AN, 2011, MATER PLAST, V48, P138

← 1 2 3 4 5 →