Synthesis of porphyrin dimers using a Heck-type coupling reaction with bisacrylates

被引:21
作者
Risch, N [1 ]
Gauler, R [1 ]
Keuper, R [1 ]
机构
[1] Univ Gesamthsch Paderborn, Fachbereich Chem & Chemietechn, D-33098 Paderborn, Germany
关键词
Heck reaction; dimeric porphyrins; photodynamic therapy; palladium(0)-catalyzed C-C coupling;
D O I
10.1016/S0040-4039(99)00418-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Heck-type crosscoupling reaction in DMF under phase-transfer conditions of zinc(II)-monobromo-deuteroporphyrin-dimethylester (1) and several bifunctional alpha,beta-unsaturated carbonyl compounds 3a-e provided C-C-linked dimeric porphyrins, an important class of photosensitizers. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2925 / 2926
页数:2
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