Magnetic properties of epsilon-Fe2O3 nanoparticles supported on silica with the average size of few nanometers, narrow size distribution and no admixture of any other iron oxide polymorphs are investigated. The investigation of the temperature behavior of magnetization within the temperature range from 4.2 to 1000 K revealed the presence of several magnetic subsystems in the species under study. The temperatures' behavior of the magnetic moment value indicates ferrimagnetic ordering in the epsilon-Fe2O3 nanoparticles with a Curie temperature of about 800 K and points to the existence of a significant paramagnetic contribution becoming apparent at low temperatures. According to the electron spin resonance data, the particles possess superparamagnetic behavior at temperature higher similar to 120K. The model of the magnetic structure of monophase system of few nanometers epsilon-Fe2O3 nanoparticles supported on silica is proposed. (C) 2012 American Institute of Physics. [doi:10.1063/1.3686647]
机构:
Deakin Univ, Inst Technol Res & Innovat, Geelong, Vic 3217, AustraliaDeakin Univ, Inst Technol Res & Innovat, Geelong, Vic 3217, Australia
Tsuzuki, Takuya
Schaeffel, Franziska
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Univ Western Australia, Res Ctr Adv Mineral & Mat Proc, Crawley, WA 6009, Australia
Univ Oxford, Dept Mat, Oxford OX1 3PH, EnglandDeakin Univ, Inst Technol Res & Innovat, Geelong, Vic 3217, Australia
Schaeffel, Franziska
Muroi, Michihito
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Antaria Ltd, Bentley, WA 6102, AustraliaDeakin Univ, Inst Technol Res & Innovat, Geelong, Vic 3217, Australia
Muroi, Michihito
McCormick, Paul G.
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Univ Western Australia, Res Ctr Adv Mineral & Mat Proc, Crawley, WA 6009, Australia
Antaria Ltd, Bentley, WA 6102, AustraliaDeakin Univ, Inst Technol Res & Innovat, Geelong, Vic 3217, Australia
机构:
Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R ChinaChinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
Liu, Zhong
Ding, Xiuping
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Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R ChinaChinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
Ding, Xiuping
Yu, Ruitao
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Chinese Acad Sci, Northwest Plateau Biol Inst, Xining 810008, Qinghai, Peoples R ChinaChinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
Yu, Ruitao
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