Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate

被引：3

作者：

Zhang, Gang ^{[1
]}

Wang, Yong ^{[2
]}

机构：

[1] Henan Univ Urban Construct, Dept Chem & Chem Engn, Pingdingshan, Henan, Peoples R China

[2] Henan Polytech Inst, Dept Chem Engn, Nanyang 473009, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

FRAMEWORKS;

D O I：

10.1107/S1600536811020071

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Mn(C7H7N2O4)(2)(H2O)(2)]center dot 2C(3)H(7)NO, the central Mn-II ion, located on an inversion center, is hexacoordinated by four O atoms from two water molecules and two carboxylate groups, and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anions in a slightly distorted octahedral environment. The complex molecules and solvent molecules are connected via N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a two-dimensional polymeric structure parallel to (001).

引用

页码：M828 / U192

页数：9

共 7 条

[1]

Bruker, 2007, APEX2 SAINT

[2] Poly[[[diaquasodium]-μ3-5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ4N3,O4:O5:O5] monohydrate] [J].

Li, Shi-Jie ;

Ma, Xiao-Tian ;

Song, Wen-Dong ;

Li, Xiao-Fei ;

Liu, Juan-Hua .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :M295-U171

[3]

Sheldrick G.M., 1996, SADABS

[4] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[5] Assembly of two 3-D metal-organic frameworks from Cd(II) and 4,5-imidazoledicarboxylic acid or 2-ethyl-4,5-imidazoledicarboxylic acid [J].

Wang, Shuang ;

Zhang, Lirong ;

Li, Guanghua ;

Huo, Qisheng ;

Liu, Yunling .

CRYSTENGCOMM, 2008, 10 (11) :1662-1666

[6] Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate [J].

Yan, Jian-Bin ;

Li, Shi-Jie ;

Song, Wen-Dong ;

Wang, Hao ;

Miao, Dong-Liang .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M99-U1026

[7] Four Novel Frameworks Built by Imidazole-Based Dicarboxylate Ligands: Hydro(Solvo)thermal Synthesis, Crystal Structures, and Properties [J].

Zhang, Fuwei ;

Li, Zifeng ;

Ge, Tiezhu ;

Yao, Hongchang ;

Li, Gang ;

Lu, Huijie ;

Zhu, Yanyan .

INORGANIC CHEMISTRY, 2010, 49 (08) :3776-3788

← 1 →