Synthesis of porphyrin-fullerene dyads and their spectroscopic properties

被引：11
|
作者：
Leupold, Stephan [1 ]
Shokati, Touraj [1 ,2 ,3 ]
Eberle, Christoph [1 ]
Borrmann, Tobias [1 ]
Montforts, Franz-Peter [1 ]
机构：
[1] Univ Bremen, Inst Organ Chem, D-28359 Bremen, Germany
[2] Univ Colorado, Dept Anesthesiol, Denver, CO 80262 USA
[3] Univ Colorado, Hlth Sci Ctr, Denver, CO 80262 USA
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 15期
关键词：
porphyrinoids; fullerenes; dyads; cycloaddition; atropisomerism; photosynthesis;
D O I：
10.1002/ejoc.200800054
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Porphyrin-fullerene dyads with different linkages between the two subunits were synthesized for mimicking photosynthesis. NMR spectra and quantum mechanical calculations show special structural features that should influence light-induced electron transfer of the photosynthetic process. Starting point of the synthetic routes is a deuterioporphyrin dimethyl ester prepared from the readily accessible blood pigment heme. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
引用
收藏
页码：2621 / 2627
页数：7
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