Pore-scale lattice Boltzmann simulation of two-component shale gas flow

Shale gas is usually a multi-component gas mixture dominated by CH4. Moreover, CO2 sequestration in shale reservoirs and CO2-enhanced shale-gas recovery also result in multi-component gas flow in shale reservoirs. Therefore, compared with single-component gas flow, multi-component gas flow is more often encountered in practice. Furthermore, shale rock contains a lot of nano-pores in which the micro-scale effect makes the multicomponent gas flow become more complex. In this paper, the lattice Boltzmann method is employed to simulate the two-component shale gas flow in a two-dimensional micropore under different conditions. The pore-scale transport mechanism of the two-component shale gas is investigated and the gas separation phenomenon for the shale gas flow is discussed in detail. It is found that the molar fraction of each species in shale gas does not distribute uniformly along the micropore and the gas separation phenomenon exists in the two-component pressure-driven shale gas flow. The molar fraction distribution of each species along the micropore is affected by the Knudsen number, pressure ratio, shale gas composition and molar fraction of each species for the pressure-driven gas flows. In particular, we find that the molar fraction distribution and pressure distribution for two-component shale gas along the micropore are related to the pressure ratio and are unrelated to the pressure gradient. With increasing the molar fraction of CH4 in shale gas, both the gas-mixture velocity at the outlet and the slip velocity along the micropore become larger. Both the Knudsen number and pressure ratio affect the molar fraction distribution of CO2 for the CH4-CO2 mixture in the micropore during CO2 injection, while the influence of them works oppositely. Furthermore, the concentration diffusion without the external force is affected by the micropore width and the concentration difference between the gas mixtures.