Photochemical synthesis and optical properties of high membered thiohelicenes

被引:17
作者
Caronna, T
Sinisi, R
Catellani, M
Luzzati, S
Abbate, S
Longhi, G
机构
[1] Univ Brescia, Dip Sci Biomed & Biotecnol, I-25124 Brescia, Italy
[2] Politecn Milan, Dipartimento Chim, I-20131 Milan, Italy
[3] CNR, Ist Chim Macromol, I-20133 Milan, Italy
关键词
thiohelicenes; photochemistry; synthesis; absorption; emission; circular dicroism;
D O I
10.1016/S0379-6779(00)00749-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A general photochemical synthesis of large thiohelicenes composed containing 5, 7, 9 and 11 rings is presented. The absorption and emission properties of the racemic molecules are discussed along with the chirooptical properties of two enantiomers.
引用
收藏
页码:79 / 80
页数:2
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