Computer-Assisted Design of Ionic Liquids for Efficient Synthesis of 3(2H)-Furanones: A Domino Reaction Triggered by CO2

被引：71

作者：

Chen, Kaihong ^{[1
]}

Shi, Guiling ^{[1
]}

Zhang, Weidong ^{[1
]}

Li, Haoran ^{[1
]}

Wang, Congmin ^{[1
,2
]}

机构：

[1] Zhejiang Univ, Dept Chem, ZJU NHU United R&D Ctr, Hangzhou 310027, Zhejiang, Peoples R China

[2] Zhejiang Univ, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 43期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; FACILE SYNTHESIS; CAPTURE; TRANSFORMATION; ACTIVATION; BASICITY; CYCLOADDITION; CYCLIZATION; ABSORPTION; CATALYSIS;

D O I：

10.1021/jacs.6b08895

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A strategy for the highly efficient synthesis of 3(2H)-furanones by hydration of diyne alcohols catalyzed by base-functionalized ionic liquids under atmospheric-pressure CO2 that was developed through computer-assisted design is reported. The best range of basic ionic liquids as catalysts was predited at first, and [HDBU] [BenIm] exhibited the highest catalytic activity. Through a combination of. NMR spectroscopic investigations and quantum-chemical calculations, the results indicated the importance of the basicity of the anion and the species of cation in the ionic liquid.

引用

页码：14198 / 14201

页数：4

共 50 条

[31] Halogen Bonding Interactions between Brominated Ion Pairs and CO2 Molecules: Implications for Design of New and Efficient Ionic Liquids for CO2 Absorption [J].

Zhu, Xiang ;

Lu, Yunxiang ;

Peng, Changjun ;

Hu, Jun ;

Liu, Honglai ;

Hu, Ying .

JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (14) :3949-3958

[32] Simultaneous and exceptionally efficient removal of H2S and CO2 from CH4 by novel protic thiolate ionic liquids [J].

Lan, Hongchao ;

Shi, Mingzhen ;

Hu, Xingbang ;

Wu, Youting .

CHEMICAL ENGINEERING JOURNAL, 2025, 518

[33] H2S-CO2 gas separation with ionic liquids on low ratio of H2S/CO2 [J].

Adhi, Tri Partono ;

Situmorang, Yohanes Andre ;

Winoto, Haryo Pandu ;

Ariono, Danu ;

Septiana, Diannisa ;

Imanuela, Patricia ;

Indarto, Antonius .

HELIYON, 2021, 7 (12)

[34] Machine Learning-Based Design of Ionic Liquids at the Atomic Scale for Highly Efficient CO2 Capture [J].

Liu, Xiangyang ;

Chu, Jianchun ;

Huang, Shaoxuan ;

Li, An ;

Wang, Shuanlai ;

He, Maogang .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (24) :8978-8987

[35] Protic ionic liquids-promoted efficient synthesis of quinazolines from 2-aminobenzonitriles and CO2 at ambient conditions [J].

Lang, Xian-Dong ;

Yu, Yi-Chen ;

Li, Zheng-Ming ;

He, Liang-Nian .

JOURNAL OF CO2 UTILIZATION, 2016, 15 :115-122

[36] Construction of ZIF-8 and amino functionalized porous ionic liquids for efficient CO2 capture [J].

Yang, Jiaxi ;

Gao, Dan ;

Zhang, Heng ;

Yi, Qun .

FUEL, 2024, 366

[37] A facile base-promoted domino Michael/O-alkylation reaction for the construction of succinimide-substituted 3(2H)-furanones [J].

Wang, Wu ;

Liang, Guojuan ;

Bai, Yan ;

Bai, Lijuan ;

Zhou, Hui ;

Yu, Yu ;

Zhou, Jing .

ARKIVOC, 2017, :236-248

[38] CO2/CH4 and H2S/CO2 Selectivity by Ionic Liquids in Natural Gas Sweetening [J].

Wang, Lan-yun ;

Xu, Yong-liang ;

Li, Zhen-dong ;

Wei, Ya-nan ;

Wei, Jian-ping .

ENERGY & FUELS, 2018, 32 (01) :10-23

[39] Surface engineering of α-Al2O3 nanosheets with highly dispersed poly(ionic liquids) for selective CO2 adsorption [J].

Guo, Qirui ;

Yao, Yuan ;

Liu, Jiancheng ;

Zhang, Xuehua ;

Shi, Weizhong ;

Meng, Jie ;

Wang, Yuan ;

Wan, Hui ;

Guan, Guofeng .

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2023, 170 :267-276

[40] Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids [J].

Wang, Jin-Quan ;

Cheng, Wei-Guo ;

Sun, Jian ;

Shi, Tian-Yuan ;

Zhang, Xiang-Ping ;

Zhang, Suo-Jiang .

RSC ADVANCES, 2014, 4 (05) :2360-2367

← 1 2 3 4 5 →