Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

被引：503
作者：
Gross, Adam F. [1 ]
Sherman, Elena [1 ]
Vajo, John J. [1 ]
机构：
[1] HRL Labs LLC, Malibu, CA 90265 USA
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 18期
关键词：
METAL-ORGANIC FRAMEWORKS; IMIDAZOLATE FRAMEWORKS; CAPTURE PROPERTIES; TOPOLOGIES; SEPARATION; ZIF-8;
D O I：
10.1039/c2dt30174a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.
引用
收藏
页码：5458 / 5460
页数：3
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