Bis(pentane-2,4-dionato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cobalt(II)

被引：4
作者：
Perdih, Franc [1 ,2 ]
机构：
[1] Univ Ljubljana, Fac Chem & Chem Technol, SI-1000 Ljubljana, Slovenia
[2] CO EN FIST, SI-1000 Ljubljana, Slovenia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 17.1; mean σ(C-C) = 0.002 Å; R factor = 0.032; single-crystal X-ray study; T = 293 K; wR factor = 0.089;
D O I：
10.1107/S1600536811046216
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(C5H7O2)(2)(C12H8N2)], the Co-II cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octahedral environment, with Co-O bond lengths of 2.0565 (11) and 2.0641 (11) angstrom and Co-N bond lengths of 2.1630 (12) angstrom. In the crystal, there are no significant hydrogen-bonding or pi-pi interactions.
引用
收藏
页码：M1697 / U145
页数：8
相关论文
共 50 条
  • [21] Diiodido(1,10-phenanthroline-5,6-dione-κ2N,N′)mercury(II)
    Ghaemi, Akbar
    Shojaiean, Rezvan
    Ng, Seik Weng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1449 - U1356
  • [22] Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
    Wang, Aidong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M43 - +
  • [23] Diaquabis(pyridine-2-sulfonato-κ2N,O)cobalt(II)
    Li, Zong-Sheng
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1781 - U2111
  • [24] catena-Poly[[(1,10-phenanthroline-kappa N-2,N') lead(II)]-di-mu-nitrato-kappa O-3, O':O ''; kappa O-3:O',O ''-[(1,10-phenanthroline-kappa N-2,N') lead(II)]-bis(mu-2,2,2-trichloro-acetato-kappa O-2:O')]
    Shahverdizadeh, Gholam Hossein
    Ng, Seik Weng
    Tiekink, Edward R. T.
    Mirtamizdoust, Babak
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M237 - U339
  • [25] Bis(2,2′-bipyridine N-oxide-κ2O,N)-copper(II) β-octamolybdate
    Yuan, Ji-Hong
    Wang, Cheng
    Sun, Zhi-Yao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1399 - U173
  • [26] N,N′-bis(2-ammonioethyl)oxamide diaquabis(oxalato-κ2O,O′)cuprate(II) dihydrate
    Zhu, Chun-Yuan
    Li, Yan-Tuan
    Wu, Zhi-Yong
    Sun, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M3585 - M3587
  • [27] (Nitrato-kappa O-2,O')bis(1,1'-phenanthroline-kappa(2) N, N') copper(II) tricyanomethanide
    Lackova, Katarina
    Potocnak, Ivan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1553 - +
  • [28] Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-furan-2-carboxylato-κ2O:O′)cadmium(II)]
    Chen, Man-Sheng
    Zhang, Chun-Hua
    Kuang, Dai-Zhi
    Feng, Yong-Lan
    Deng, Yi-Fang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1290 - M1291
  • [29] Tris(1,10-phenanthroline-kappa N-2, N ')-ruthenium(II)bis(perchlorate)
    Kozlowska, Mariana
    Rodziewicz, Pawel
    Brus, Diana Malgorzata
    Czyrko, Justyna
    Brzezinski, Krzysztof
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1570 - +
  • [30] Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate
    Wang, Hui
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M95 - U203
12345