Efficient intramolecular general acid catalysis of the hydrolysis of a dialkyl acetal

被引：3
|
作者：
Brown, CJ [1 ]
Kirby, AJ [1 ]
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 20期
关键词：
D O I：
10.1039/cc9960002355
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrolysis of benzaldehyde acetal 3, catalysed by the neighbouring carboxy group, is some 10(5) times faster than that of a comparable system 6, which does not form a strong intramolecular hydrogen bond in the transition state for the reaction.
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页码：2355 / 2356
页数：2
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