Synthesis of novel 1,2,3-triazole based polycarboxylic acid functionalised ligands for MOF systems

被引：11

作者：

Belay, Yonas ^{[1
]}

Coetzee, Louis-Charl ^{[1
]}

Williams, D. Bradley G. ^{[2
]}

Muller, Alfred ^{[1
]}

机构：

[1] Univ Johannesburg, Dept Chem, POB 524, ZA-2006 Auckland Pk, South Africa

[2] Univ Technol Sydney, Sch Math & Phys Sci, POB 123, Sydney, NSW 2007, Australia

来源：

TETRAHEDRON LETTERS | 2019年 / 60卷 / 06期

基金：

新加坡国家研究基金会;

关键词：

Click reaction; Azoles; 1,2,3-Triazole; CLICK;

D O I：

10.1016/j.tetlet.2019.01.014

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper catalysed click reactions are excellent tools to generate various 1,2,3-triazole linked polytopic aromatic carboxylates, The general reaction route involves protection of the carboxylates before proceeding with the click reaction. These polycarboxylate azoles are conveniently prepared for potential utility as novel key building blocks for metal organic frameworks. In one case, the ligand crystallises into a solid structure containing 1D, 2D and 3D features, based on a zigzag 1D structure, a 'chicken mesh'-like 2D structure and a 3D structure with very well-defined channels. (C) 2019 Published by Elsevier Ltd.

引用

页码：501 / 503

页数：3

共 15 条

[11] "Click" on MOFs: A Versatile Tool for the Multimodal Derivatization of N3-Decorated Metal Organic Frameworks [J].