A quarter of a century of SERF: The progress of an NMR pulse sequence and its application

被引:14
作者
Berger, Stefan [1 ]
机构
[1] Univ Leipzig, Inst Analyt Chem, Johannisallee 29, D-04103 Leipzig, Germany
关键词
NMR spectroscopy; Selective pulse methods; Total; scalar and dipolar coupling; Structure elucidation; PURE-SHIFT NMR; COUPLING-CONSTANTS; DIPOLAR COUPLINGS; ENANTIOMERIC MIXTURES; COMPLETE ERADICATION; SCALAR INTERACTIONS; H-1-NMR SPECTRA; AXIAL PEAKS; SPECTROSCOPY; HOMONUCLEAR;
D O I
10.1016/j.pnmrs.2018.10.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SERF, an NMR pulse sequence for selectively measuring a spin coupling constant without interference from other couplings, was published by the current author almost 25 years ago in 1995. Since then, about 35 modifications and extensions of the original have been published by other groups and applied to many chemical problems. This review discusses these modifications and provides pertinent examples. A comparative and critical evaluation of these developments is given in tabular form. The last part focuses on the chemical results. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:74 / 114
页数:41
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