Emulsion stabilization by solid particles - A two-layer approach: Spherical particles

被引：13

作者：

Friberg, SE ^{[1
]}

机构：

[1] Clarkson Univ, Dept Chem, Potsdam, NY USA

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2005年 / 26卷 / 06期

关键词：

D O I：

10.1081/DIS-200062921

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The displacement energy for two layers of particles at an O/W interface was calculated for configurations in which the contact angle is different for the two kinds of particles, both with regular lateral organization. The radius of the particles is assumed sufficiently small in comparison with the drop radius to use a surface without curvature for the calculations. The results show conditions under which the presence of the second layer enhances the energy resisting coalescence of the drops.

引用

收藏

页码：647 / 654

页数：8

相关论文

共 27 条

[1] Stabilization of emulsions by heterocoagulation of clay minerals and layered double hydroxides [J].

Abend, S ;

Bonnke, N ;

Gutschner, U ;

Lagaly, G .

COLLOID AND POLYMER SCIENCE, 1998, 276 (08) :730-737

[2] Aspects of the stabilisation of emulsions by solid particles: Effects of line tension and monolayer curvature energy [J].

Aveyard, R ;

Clint, JH ;

Horozov, TS .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (11) :2398-2409

[3] Novel emulsions of ionic liquids stabilised solely by silica nanoparticles [J].

Binks, BP ;

Dyab, AKF ;

Fletcher, PDI .

CHEMICAL COMMUNICATIONS, 2003, (20) :2540-2541

[4] Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica [J].

Binks, BP ;

Lumsdon, SO .

LANGMUIR, 2000, 16 (06) :2539-2547

[5] Interfacial structure of solid-stabilised emulsions studied by scanning electron microscopy [J].

Binks, BP ;

Kirkland, M .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (15) :3727-3733

[6] Particles adsorbed at the oil-water interface: A theoretical comparison between spheres of uniform wettability and "Janus" particles [J].

Binks, BP ;

Fletcher, PDI .

LANGMUIR, 2001, 17 (16) :4708-4710

[7] Influence of particle wettability on the type and stability of surfactant-free emulsions [J].

Binks, BP ;

Lumsdon, SO .

LANGMUIR, 2000, 16 (23) :8622-8631

[8] Particles as surfactants - similarities and differences [J].

Binks, BP .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41

[9] A POSSIBLE MECHANISM OF STABILIZATION OF EMULSIONS BY SOLID PARTICLES [J].

DENKOV, ND ;

IVANOV, IB ;

KRALCHEVSKY, PA ;

WASAN, DT .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 150 (02) :589-593

[10]

HANNISDAL A, IN PRESS COLLOIDS SU