Asymmetric hydrogenation of α-keto phosphonates with chiral phosphine-phosphoramidite ligands

被引：10
作者：
Li, Qing [1 ,2 ]
Hou, Chuan-Jin [1 ,2 ]
Liu, Yan-Jun [1 ]
Yang, Rui-Feng [1 ]
Hu, Xiang-Ping [2 ]
机构：
[1] Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
TETRAHEDRON-ASYMMETRY | 2015年 / 26卷 / 12-13期
基金：
中国国家自然科学基金;
关键词：
CATALYZED ENANTIOSELECTIVE HYDROGENATION; HYDROXY PHOSPHONATES; BETA-KETOESTERS; AL(SALALEN) COMPLEX; DIPHOSPHINE LIGANDS; KINETIC RESOLUTION; N-ARYLIMINES; HYDROPHOSPHONYLATION; ALDEHYDES; HYDROXYPHOSPHONATES;
D O I：
10.1016/j.tetasy.2015.05.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rh-catalyzed asymmetric hydrogenation of challenging alpha-keto phosphonates has been developed. With a new chiral phosphine-phosphoramidite ligand, a wide range of alpha-keto phosphonates were hydrogenated to afford the corresponding (R)-alpha-hydroxy phosphonates with moderate to good enantioselectivities (up to 87% ee). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：617 / 622
页数：6
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