Enhancement on the exchange coupling behavior of SrCo0.02Zr0.02Fe11.96O19/MFe2O4 (M = Co, Ni, Cu, Mn and Zn) as hard/soft magnetic nanocomposites

被引:78
作者
Algarou, N. A. [1 ,2 ]
Slimani, Y. [1 ]
Almessiere, M. A. [1 ,2 ]
Baykal, A. [3 ]
Guener, Sadik [4 ]
Manikandan, A. [5 ]
Ercan, I [1 ]
机构
[1] Imam Abdulrahman Bin Faisal Univ, IRMC, Dept Biophys, POB 1982, Dammam 31441, Saudi Arabia
[2] Imam Abdulrahman Bin Faisal Univ, Coll Sci, Dept Phys, POB 1982, Dammam 31441, Saudi Arabia
[3] Imam Abdulrahman Bin Faisal Univ, IRMC, Dept Nanomed Res, POB 1982, Dammam 31441, Saudi Arabia
[4] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany
[5] Bharath Inst Higher Educ & Res, Dept Chem, Chennai, Tamil Nadu, India
关键词
Hard-soft ferrites; Spinel ferrites; Hexaferrites; Exchange coupling; One pot synthesis; Sol-gel auto-combustion; STRONTIUM HEXAFERRITE; MICROWAVE-ABSORPTION; MAGNETOOPTICAL PROPERTIES; FERRITE NANOPARTICLES; ELECTRICAL-PROPERTIES; SOFT; SUBSTITUTION; HARD; SITE; TEMPERATURE;
D O I
10.1016/j.jmmm.2019.166308
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hard/soft SrCo0.02Zr0.02Fe11.96O19/MFe2O4 (M = Ni, Co, Cu, Mn and Zn) nanocomposites have been fabricated efficiently via one-pot sol-gel combustion route. The influence of different type of spinel were examined by XRD (X-ray diffraction), SEM - TEM (scanning and transmission electron microscopies) systems and VSM (vibrating sample magnetometer). The XRD investigation of Hard/soft nanocomposites revealed the tailoring between hexaferrite and spinel ferrite phases. Magnetization measurements (M vs. H) were performed at room (T = 300 K) and low temperature (T = 10 K) and diverse magnetic parameters comprising M, (saturation magnetization), M-r (remanence), coercivity (H-c), and so on were determined. Smooth M vs. H curves and single peaks in dM/dH vs. H plots were observed for various prepared nanocomposites. The Henkel plots and maximum energy products were also determined and analyzed. Various prepared hard/soft nanocomposites indicated relatively high values of diverse magnetic parameters. Diverse findings disclosed the incidence of exchange-coupling spring behavior among various soft and hard magnetic phases. Measurements of ZFC-FC magnetizations showed the existence of a peak temperature values, which are largely ascribed to competition between the motion of magnetic domain walls and thermal activations. It is revealed that one-pot sol-gel combustion route is valuable to attain strong exchange coupling among hard and soft nanoparticle phases grown near to each other. The obtained findings indicated that these nanocomposites are promising candidates for numerous practical applications.
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页数:14
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