Synthesis, Crystal Structure and Properties of a Zinc(II) Complex Based on 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand

被引：0
作者：
Zhang Xing-Jing [1 ,2 ]
Wang Lu-Yao [1 ]
Wei Bing [1 ]
Li Meng [1 ]
Qiao Yu [1 ,2 ]
Che Guang-Bo [1 ,2 ]
机构：
[1] Jilin Normal Univ, Coll Chem, Siping 136000, Peoples R China
[2] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Chinese Minist Educ, Siping 136000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 35卷 / 08期
基金：
中国国家自然科学基金;
关键词：
zinc(II) complex; crystal structure; 5-(1H-tetrazol-5-yl)isophthalic acid; photoluminescence; METAL-ORGANIC FRAMEWORKS; ADSORPTION; SERIES;
D O I：
10.14102/j.cnki.0254-5861.2011-1029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel polymeric zinc(II) complex {[Zn-2(TIA)H2O)(3)].(NO3)}(n) (1, H(3)TIA = 5(1H-tetrazol-5-yl)isophthalic acid) has been synthesized in mixed solvents under solvothermal conditions and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Complex 1 crystallizes in orthorhombic, space group Cmcm with a = 10.4210(6), b = 23.3526(14), c = 6.9214(4) angstrom, v = 1684.37(17) angstrom(3), Z = 4, C9H4N5O10Zn2, M-r = 472.91, D-c = 1.865 g/cm(3), F(000) = 932, lambda(MoKa) = 2.909 mm(-1), R = 0.0423 and wR = 0.1287. The complex has good thermal stability and excellent photoluminescent property.
引用
收藏
页码：1213 / 1221
页数：9
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