Comment on "Liquid-Gas Interface of Iron Aqueous Solutions and Fenton Reagents"

被引：1

作者：

Colussi, Agustin J. ^{[1
]}

Enami, Shinichi ^{[2
]}

机构：

[1] CALTECH, 1200 East Calif Blvd, Pasadena, CA 91125 USA

[2] Natl Inst Environm Studies, 16-2 Onogawa, Tsukuba, Ibaraki 3058506, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2022年 / 13卷 / 29期

关键词：

CHEMISTRY;

D O I：

10.1021/acs.jpclett.2c01006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A recent Letter in this Journal (Gladich et al. J. Phys. Chem. Lett. 13, 2994-3001) reported that photoelectron spectroscopy could not detect any products on the surface of aqueous Fe2+ jets dosed with gaseous hydrogen peroxide. The Letter however concluded that Fe(aq)(2+) ions react with H2O2(g) at the water-vapor interface to produce the same Fe3+ + HO center dot products as their reaction with H2O2(aq) in bulk water. We argue that this conclusion is untenable because nothing can be asserted about undetected species.

引用

页码：6680 / 6680

页数：1

共 4 条

[1] Surface enhancement of water at the ionic liquid-gas interface of [HMIM][Cl] under ambient water vapor
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[2] Surface Propensity of Aqueous Atmospheric Bromine at the Liquid- Gas Interface
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[3] Imaging the oxidation effects of the Fenton reaction on phospholipids at the interface between aqueous phase and thermotropic liquid crystals
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[4] Characterization of Fe2+ Aqueous Solutions with Liquid Jet X-ray Photoelectron Spectroscopy: Chloride Depletion at the Liquid/Vapor Interface Due to Complexation with Fe2+
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