Investigations on the mechanical properties of hybrid nanocomposite hard coatings on polycarbonate

Hybrid nanocomposite coatings derived from titanium tetraisopropoxide and epoxy or acrylic modified silanes were deposited on polycarbonate (PC) by dip coating employing various withdrawal speeds followed by ultraviolet and thermal curing. The effect of different organic functional groups in the precursors and ageing effect of these sols were systematically studied with respect to thickness, abrasion resistance, pencil scratch test, nanoindentation hardness and transmittance. The gels derived from the freshly prepared and aged sols were structurally characterized by FT-IR and TEM analysis. The viscosities of the sols were monitored with time. The change in viscosity is rapid for sol from epoxy modified silane. The thickness of the coatings increases with increase in viscosity in case of both the silane precursors. The scratch as well as abrasion resistance increases as a function of coating thickness. The pencil scratch hardness improves from 2B for the bare PC to a maximum of 3H for the coating obtained from an aged sol derived from epoxy modified silane. Also, the abrasion resistance of the coatings from same sol was maximum as evidenced by a <6% change in haze after 500 cycles, vis-a-vis 40% for the bare PC. The coatings from a freshly prepared sol of acrylic modified silane and titania showed the maximum nanoindentation hardness of 0.52 GPa, when compared to 0.23 GPa for the bare PC. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.