Chiral quaternary phosphonium salts: a new class of organocatalysts

被引：117

作者：

Enders, Dieter ^{[1
]}

Thanh Vinh Nguyen ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 28期

关键词：

PHASE-TRANSFER CATALYSTS; DIRECT HENRY REACTION; ALDOSE REDUCTASE INHIBITOR; HYDROGEN-BONDING SITE; BETA-KETO-ESTERS; ASYMMETRIC-SYNTHESIS; ARYLAMINOPHOSPHONIUM BARFATES; TETRAAMINOPHOSPHONIUM SALTS; TRANSFER ALKYLATION; FLUSTRA-FOLIACEA;

D O I：

10.1039/c2ob25823d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phase-transfer catalysis has widely been used as a prime synthetic tool for both laboratory and industrial processes. During the last twenty years, asymmetric phase-transfer catalysis using chiral organocatalysts has attracted widespread interest. However, the scope of chiral phase-transfer catalysis has been limited mostly to the quaternary ammonium salts. As an emerging area, the recent developments in the application of quaternary phosphonium salts as chiral phase-transfer catalysts are discussed in this article.

引用

页码：5327 / 5331

页数：5

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