Studies on synthesis, characterization and thermochemistry of Mg2[B2O4(OH)2]•H2O

被引：12
作者：
Zhihong, L [1 ]
Mancheng, H [1 ]
Shiyang, G [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2004年 / 75卷 / 01期
关键词：
Mg-2[B2O4(OH)(2)]H2O; solution calorimetry; standard molar enthalpy of formation; synthesis;
D O I：
10.1023/B:JTAN.0000017329.58812.20
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A new magnesium borate Mg-2[B2O4(OH)(2)] . H2O has been synthesized by the method of phase transformation of double salt at hydrothermal condition and characterized by XRD, IR, TG and DSC. The enthalpy of solution of Mg-2[B2O4(OH)(2)] . H2O in 0.9764 mol L-1 HCl was determined. With the incorporation of the enthalpies of solution of H3BO3 in HCl (aq), of MgO in (HCl+H3BO3) (aq), and the standard molar enthalpies of formation of MgO(s), H3BO3(s), and H2O(l), the standard molar enthalpy of formation of -(3185.78 +/- 1.91) kJ mol(-1) of Mg-2[B2O4(OH)(2)] . H2O was obtained.
引用
收藏
页码：73 / 78
页数：6
相关论文
共 50 条
  • [31] Synthesis and characterization of a one-dimensional chain polymer {[Cu(4-CPOA)(3-PyOH)2(H2O)2]•H2O}n
    Gao, S
    Huo, LH
    Liu, JW
    Gu, CS
    Zhao, H
    Zhao, JG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (07) : 755 - 758
  • [32] Synthesis and Characterization of a One-dimensional Chain Polymer{[Cu（4-CPOA）(3-PyOH)2（H2O）2]·H2O}n
    GAO Shana HUO Li-Huaa LIU Ji-Weia
    Chinese Journal of Structural Chemistry, 2005, (07) : 755 - 758
  • [33] Thermochemistry of 2MgSO4•MgO•3H2O
    Yue, T
    Zhu, LX
    Xia, SP
    THERMOCHIMICA ACTA, 2005, 426 (1-2) : 49 - 52
  • [34] Synthesis and Crystal Structures of Two New Supramolecular Complexes: [Cu(tmbpm)(ox)(H2O)]•4H2O and [Zn(tmbpm)2(H2O)]•(ClO4)2•5H2O
    Ma, N.
    Ji, B. M.
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (01) : 106 - 111
  • [35] Synthesis and the network structure of the supramolecular compound [NEt4][Mn(salophen)(H2O)2]2[Fe(CN)6]•H2O•CH3OH
    Li, SN
    Li, J
    Tang, ZX
    Zhou, ZY
    ACTA CHIMICA SINICA, 2001, 59 (01) : 78 - 83
  • [36] Synthesis and characterization of 2D layered structure decavanadate [K(H2O)2Ni(H2O)6]2[V10O28]
    Li, DH
    Liu, SX
    Peng, J
    Shao, KZ
    Xu, HB
    Zhai, HJ
    Wang, EB
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (09) : 1076 - 1080
  • [37] Synthesis, structure and characterization of a novel decavanadate, Mg(H2O)6(C4N2H7)4V10O28•4H2O, with a potential antitumor activity
    Louati, Myriam
    Ksiksi, Regaya
    Elbini-Dhouib, Ines
    Mlayah-Bellalouna, Saoussen
    Doghri, Raoudha
    Srairi-Abid, Najet
    Zid, Mohamed-Faouzi
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1242
  • [38] Thermodynamic properties of Cs2[B4O5(OH)4] • 3H2O
    Liu, ZH
    Li, SY
    Hu, MC
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (09) : 1003 - 1006
  • [39] Studies on synthesis, crystal structure and thermal decomposition mechanism of cadmium complex [Cd(ATZ)4(H2O)2] (PA)2 •2H2O
    Zhang, JG
    Zhang, TL
    Yu, KB
    ACTA CHIMICA SINICA, 2001, 59 (01) : 84 - 90
  • [40] Synthesis, crystal structure and magnetic property of [Ho2 (phen)4(H2O)4 OH)2](phen)2(NO3)4
    Wei, DY
    Zheng, YQ
    Lin, JL
    ACTA CHIMICA SINICA, 2002, 60 (07) : 1248 - 1252
12345