Inverted aggregates of luminescent ruthenium metallosurfactants

被引：31

作者：

Dominguez-Gutierrez, David ^{[1
,2
]}

De Paoli, Gabriele ^{[1
]}

Guerrero-Martinez, Andres ^{[1
]}

Ginocchietti, Gabriella ^{[1
]}

Ebeling, Daniel ^{[1
]}

Eiser, Erika ^{[2
]}

De Cola, Luisa ^{[1
]}

Elsevier, Cornelis J. ^{[2
]}

机构：

[1] Univ Munster, Inst Phys, D-48149 Munster, Germany

[2] Univ Amsterdam, Vant Hoff Inst Mol chem, NL-1018 WV Amsterdam, Netherlands

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2008年 / 18卷 / 24期

关键词：

D O I：

10.1039/b717859j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metallosurfactants and their resulting aggregates combine unique spectroscopic and reactivity properties due to space confinement. We have found the requirements to obtain the first inverted micelles with luminescent metallosurfactants. The compounds possess several long linear chains that favour the solubility of the highly water-soluble metal polar head in non-polar phases. The size and shape of the aggregates have been determined using dynamic light scattering. Atomic force microscopy allowed us to study the dry structure of the aggregates on surfaces. Additionally, the self-assembly of the metal complexes in solution have been monitored by steady state and time-resolved absorption and emission spectroscopy.

引用

页码：2762 / 2768

页数：7

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