Enhanced Copolymer Gel Modified by Dual Surfactants for Flexible Zinc-Air Batteries

被引:24
作者
Zhang, Pengfei [1 ]
Wang, Keliang [1 ,2 ]
Zuo, Yayu [1 ]
Wei, Manhui [1 ]
Wang, Hengwei [1 ]
Chen, Zhuo [1 ]
Shang, Nuo [1 ]
Pei, Pucheng [2 ]
机构
[1] Beijing Inst Technol, Sch Mech Engn, Beijing 100081, Peoples R China
[2] Tsinghua Univ, State Key Lab Automot Safety & Energy, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
zinc-air batteries; gel electrolytes; dual surfactants; temperature adaptability; high performance; POLYMER ELECTROLYTE; OXIDE; HYDROGELS; ACID; F127;
D O I
10.1021/acsami.2c13625
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Zinc-air batteries using gels as carriers for electrolyte absorption have attracted extensive attention due to their flexibility, deformability, and high specific capacity. However, traditional mono-polymer gel electrolytes display poor mechanical properties and low ionic conductivity at wide-window temperatures. Here, the enhanced gel polymer (PAM-F/G) modified by dual surfactants is present by way of pluronic F127 and layered graphene oxide introduced into the polyacrylamide (PAM) matrix. The gel electrolyte procured by absorbing 6 M KOH exhibits improved mechanical characteristics, temperature adaptability, and a satisfactory ionic conductivity (276 mS cm-1). The results demonstrate that a flexible zinc-air battery assembled by PAM-F/G electrolyte outputs a high power density (155 mW cm-2) and can even operate reliably (>40 h) at -20 degrees C. These findings are available for promoting the research and popularization of flexible zinc-air batteries with high performance.
引用
收藏
页码:49109 / 49118
页数:10
相关论文
共 52 条
[1]   Graphene oxide: An effective ionic conductivity promoter for phosphoric acid-doped poly (vinyl alcohol) gel electrolytes [J].
Alipoori, Saeideh ;
Torkzadeh, M. M. ;
Moghadam, M. H. Mohamadzadeh ;
Mazinani, Saeedeh ;
Aboutalebi, Seyed Hamed ;
Sharif, Farhad .
POLYMER, 2019, 184
[2]   Tough interpenetrating Pluronic F127/polyacrylic acid hydrogels [J].
Baskan, Tuba ;
Tuncaboylu, Deniz C. ;
Okay, Oguz .
POLYMER, 2013, 54 (12) :2979-2987
[3]   Cobalt-based oxygen electrocatalysts for zinc-air batteries: Recent progress, challenges, and perspectives [J].
Chen, Dongfang ;
Pan, Lyuming ;
Pei, Pucheng ;
Song, Xin ;
Ren, Peng ;
Zhang, Lu .
NANO RESEARCH, 2022, 15 (06) :5038-5063
[4]   A Flexible and Safe Aqueous Zinc-Air Battery with a Wide Operating Temperature Range from-20 to 70 °C [J].
Chen, Rui ;
Xu, Xiubin ;
Peng, Siyu ;
Chen, Junmin ;
Yu, Danfeng ;
Xiao, Chuanghong ;
Li, Yunlong ;
Chen, Yanting ;
Hu, Xiaofeng ;
Liu, Mingjie ;
Yang, Hui ;
Wyman, Ian ;
Wu, Xu .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (31) :11501-11511
[5]   Small molecule-based supramolecular-polymer double-network hydrogel electrolytes for ultra-stretchable and waterproof Zn-air batteries working from-50 to 100 °C [J].
Gu, Chaonan ;
Xie, Xiao-Qiao ;
Liang, Yujia ;
Li, Jingjing ;
Wang, Hai ;
Wang, Kaifang ;
Liu, Junpeng ;
Wang, Mengke ;
Zhang, Yunfei ;
Li, Manxing ;
Kong, Huajie ;
Liu, Chun-Sen .
ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (08) :4451-4462
[6]  
He Y, 2022, CHEM ENG J, V448
[7]   In-situ observation of the gas evolution process on the air electrode of Zn-air batteries during charging [J].
He, Yi ;
Shang, Wenxu ;
Ni, Meng ;
Huang, Yiyin ;
Zhao, Hong ;
Tan, Peng .
CHEMICAL ENGINEERING JOURNAL, 2022, 427
[8]   Highly dispersible graphene oxide nanoflakes in pseudo -gel -polymer porous separators for boosting ion transportation [J].
Kim, Jin Il ;
Cho, Jae Sang ;
Wang, Dong Hwan ;
Park, Jong Hyeok .
CARBON, 2020, 166 :427-435
[9]   A simple low-cost method to prepare gel electrolytes incorporating graphene oxide with increased ionic conductivity and electrochemical stability [J].
Lai, Wei-Chi ;
Fan, Ren-Wei .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2022, 907
[10]   Flexible/Rechargeable Zn-Air Batteries Based on Multifunctional Heteronanomat Architecture [J].
Lee, Donggue ;
Kim, Hyun-Woo ;
Kim, Ju-Myung ;
Kim, Ka-Hyun ;
Lee, Sang-Young .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (26) :22210-22217