Chain oxidation initiated by OH, O(3P) radicals, thermal electrons, and O3 in electron beam irradiation of 1,2-dichloroethylenes and air mixtures

被引：12

作者：

Hakoda, T

Zhang, G

Hashimoto, S

机构：

[1] Japan Atom Energy Res Inst, Takasaki Radiat Chem Res Estab, Dept Radiat Res Environm & Resources, Takasaki, Gunma 3701292, Japan

[2] China Inst Nucl Informat, Res Dept, Beijing 100037, Peoples R China

来源：

RADIATION PHYSICS AND CHEMISTRY | 2001年 / 62卷 / 2-3期

关键词：

dichloroethylene; electron beam; volatile organic compounds; decomposition; chain reaction;

D O I：

10.1016/S0969-806X(01)00194-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron beam irradiation of trans- and cis-1,2-dichloroethylenes (cis-DCEs)-air mixtures was carried out in order to get quantitative information on chain oxidation. Decomposition of cis-DCE was initiated by OH, O(P-3) radicals, and thermal electrons and proceeded by Cl radical chain oxidation, whereas that of trans-DCE was initiated by not only the radicals and the electrons but also O-3. The chain lengths of trans-DCE by O-3 were estimated to be 6.2 +/- 0.2 independently of trans-DCE and O-3 concentrations. The decomposition mechanism was also clarified. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：243 / 252

页数：10

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