Preparation of (R)-(+)-7-oxabicyclo[2.2.1]hept-5-ene-exo-2-carboxylic acid, a precursor to substrates for the ring opening metathesis polymerization

被引：15

作者：

Schueller, CM ^{[1
]}

Manning, DD ^{[1
]}

Kiessling, LL ^{[1
]}

机构：

[1] UNIV WISCONSIN, DEPT CHEM, MADISON, WI 53706 USA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 49期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(96)02061-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(R)-(+)-7-Oxabicyclo[2.2.1]hept-5-ene-exo-2-carboxylic acid (2R), which can be transformed into carbohydrate-substituted monomer 5 appropriate for ring opening metathesis polymerization (ROMP) was prepared by an enzymatic kinetic resolution of 7-oxabicyclo[2.2.1]hept-5-ene-exo-2-carboxylic acid methyl ester [(+/-)1] with the lipase from Candida Rugosa. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：8853 / 8856

页数：4

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