Preparation of (R)-(+)-7-oxabicyclo[2.2.1]hept-5-ene-exo-2-carboxylic acid, a precursor to substrates for the ring opening metathesis polymerization

被引：15
作者：
Schueller, CM [1 ]
Manning, DD [1 ]
Kiessling, LL [1 ]
机构：
[1] UNIV WISCONSIN, DEPT CHEM, MADISON, WI 53706 USA
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 49期
基金：
美国国家卫生研究院; 美国国家科学基金会;
关键词：
D O I：
10.1016/S0040-4039(96)02061-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
(R)-(+)-7-Oxabicyclo[2.2.1]hept-5-ene-exo-2-carboxylic acid (2R), which can be transformed into carbohydrate-substituted monomer 5 appropriate for ring opening metathesis polymerization (ROMP) was prepared by an enzymatic kinetic resolution of 7-oxabicyclo[2.2.1]hept-5-ene-exo-2-carboxylic acid methyl ester [(+/-)1] with the lipase from Candida Rugosa. Copyright (C) 1996 Elsevier Science Ltd.
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收藏
页码：8853 / 8856
页数：4
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