Synthesis, spectral characterizations and biological studies of transition metal mixed ligand complexes: X-ray crystal structures of [Cu(oda)(Bipy)(H2O)]•4H2O and [VO(oda)(Bipy)]•2H2O

被引：37

作者：

Siddiqi, Zafar A. ^{[1
]}

Sharma, Prashant K. ^{[1
]}

Shahid, M. ^{[1
]}

Khalid, Mohd. ^{[1
]}

Kumar, Sarvendra ^{[1
]}

机构：

[1] Aligarh Muslim Univ, Dept Chem, Coordinat Chem Res Grp, Aligarh 202002, Uttar Pradesh, India

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2011年 / 994卷 / 1-3期

关键词：

Ternary complexes; Oxydiacetic acid; Crystal structure; Antimicrobial activities; Superoxide dismutase (SOD) activity; SUPEROXIDE-DISMUTASE ACTIVITY; TERNARY COPPER(II) COMPLEXES; (IMINODIACETATO)COPPER(II) CHELATE; PYRIDINE-2,6-DICARBOXYLIC ACID; BIOMIMETIC PROPERTIES; BINUCLEAR COMPLEXES; AUXILIARY LIGAND; SOD ACTIVITIES; COORDINATION; CHEMISTRY;

D O I：

10.1016/j.molstruc.2011.03.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ternary complexes of stoichiometries [M(oda)(Bipy)H2O]center dot xH(2)O [M = Cu (1), x = 4; Co (2), x = 2; Ni (3), x = 4 or Cr (4), x = 3] and [VO(oda)(Bipy)]center dot 2H(2)O (5), where H(2)oda = oxydiacetic acid and Bipy = 2,2'-bipyridine, were prepared and characterized employing elemental, FAB-Mass, FT-IR, EPR, H-1 and C-13 NMR spectroscopic analyses. X-ray crystallography of (1) and (5) indicated a six coordinate distorted geometry. The antimicrobial activities of the complexes were investigated against Escherichia coli (k-12), Bacillus subtilis (MTC-121). Staphylococcus aureus (IOASA-22). Salmonella typhymurium (MTCC-98), Candida albicans, Aspergillus fumigatus and Penicillium marneffei. The superoxide dismutase (SOD) mimic activity of the Cu(II) complex (1) was assessed employing NBT assay. (c) 2011 Elsevier B.V. All rights reserved.

引用

页码：295 / 301

页数：7

共 52 条

[41] DIPICOLINIC ACID GREATLY ENHANCES PRODUCTION OF SPORE PHOTOPRODUCT IN BACTERIAL-SPORES UPON UV IRRADIATION [J].

SETLOW, B ;

SETLOW, P .

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 1993, 59 (02) :640-643

[42]

Sheldrick G.M., 1997, SADABS, Empirical Absorption Correction Program

[43]

Sheldrick G. M., 1997, SHELXL-97, Programs for Crystal Structure Analysis

[44]

Siddiqi Z.A., 2009, XRAY STR ANAL ONLINE, V25, P71

[45] Synthesis, physico-chemical and spectral investigations of novel homo-bimetallic mixed-ligand complexes: 57Fe Mossbauer parameters of [Fe2(imda)2(H2O)3Cl] [J].

Siddiqi, Zafar A. ;

Shahid, M. ;

Khalid, Mohd ;

Noor, Shabana ;

Kumar, Sarvendra .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2010, 75 (01) :61-68

[46] Antimicrobial and SOD activities of novel transition metal complexes of pyridine-2,6-dicarboxylic acid containing 4-picoline as auxiliary ligand [J].

Siddiqi, Zafar A. ;

Khalid, Mohd ;

Kumar, Sarvendra ;

Shahid, M. ;

Noor, Shabana .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2010, 45 (01) :264-269

[47] Synthesis, crystal structure and in vitro antitumor activity of carboxylate bridged dinuclear organotin(IV) complexes [J].

Siddiqi, Zafar A. ;

Shahid, M. ;

Kumar, Sarvendra ;

Khalid, Mohd ;

Noor, Shabana .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (23) :3768-3774

[48] Antimicrobial and SOD activities of novel transition metal ternary complexes of iminodiacetic acid containing α-diimine as auxiliary ligand [J].

Siddiqi, Zafar A. ;

Shahid, M. ;

Khalid, Mohd. ;

Kumar, S. .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2009, 44 (06) :2517-2522

[49] E.s.r., magnetic, optical and biological (SOD and antimicrobial) studies of imidazolate bridged CuII-ZnII and CuII-NiII complexes with tris(2-amino ethyl)amine as capping ligand:: a plausible model for superoxide dismutase [J].

Singh, N ;

Shukla, KK ;

Patel, RN ;

Chauhan, UK ;

Shrivastava, R .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (13) :3111-3122

[50] The dark side of dioxygen biochemistry [J].

Valentine, JS ;

Wertz, DL ;

Lyons, TJ ;

Liou, LL ;

Goto, JJ ;

Gralla, EB .

CURRENT OPINION IN CHEMICAL BIOLOGY, 1998, 2 (02) :253-262

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