Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra -: I.: Crystal structure of chloromenite, Cu9O2(SeO3)4Cl6

被引：42

作者：

Krivovichev, SV ^{[1
]}

Filatov, SK ^{[1
]}

Semenova, TF ^{[1
]}

Rozhdestvenskaya, IV ^{[1
]}

机构：

[1] St Petersburg State Univ, Dept Crystallog, St Petersburg 199034, Russia

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1998年 / 213卷 / 12期

关键词：

D O I：

10.1524/zkri.1998.213.12.645

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of chloromenite, Cu9O2(SeO3)(4)Cl-6, a = 14.170(3) Angstrom, b = 6.262(1) Angstrom, c = 12.999(3) Angstrom, beta = 113.05(1)degrees, V = 1061.3(4) Angstrom(3), Z = 2, space group 12/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F-2) = 0.128). The structure is based on unbranched zwieier single chains (uB, 1(infinity)(1)) [O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar (uB, 1(infinity)(1)) [O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.

引用

页码：645 / 649

页数：5

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