The Origin of the Constant Phase Element

被引:132
作者
Lasia, Andrzej
机构
[1] Département de chimie, Université de Sherbrooke, Sherbrooke, J1K 2R1, QC
关键词
ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ANION-ADSORPTION; CAPACITANCE DISPERSION; FREQUENCY DISPERSION; ELECTRODE; BEHAVIOR; DISTRIBUTIONS; INTERFACES; RESPONSES; KINETICS;
D O I
10.1021/acs.jpclett.1c03782
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The constant phase element (CPE) is usually observed at solid electrodes. It is a source of controversies and misunderstandings. In this Viewpoint, theory, properties, experimental results, and the origin of the CPE are presented and discussed.
引用
收藏
页码:580 / 589
页数:10
相关论文
共 50 条
[21]   Impedance model for CdTe solar cells exhibiting constant phase element behaviour [J].
Friesen, G ;
Özsar, ME ;
Dunlop, ED .
THIN SOLID FILMS, 2000, 361 :303-308
[22]   The constant phase element reveals 2D phase transitions in adsorbate layers at the electrode/electrolyte interfaces [J].
Tymoczko, Jakub ;
Schuhmann, Wolfgang ;
Bandarenka, Aliaksandr S. .
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 27 :42-45
[23]   On the Use of the Power-Law Model for Interpreting Constant-Phase-Element Parameters [J].
Orazem, Mark E. ;
Tribollet, Bernard ;
Vivier, Vincent ;
Riemer, Douglas P. ;
White, Erick ;
Bunge, Annette .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2014, 25 (03) :532-539
[24]   Dielectric Properties of Materials Showing Constant-Phase-Element (CPE) Impedance Response [J].
Orazem, Mark E. ;
Frateur, Isabelle ;
Tribollet, Bernard ;
Vivier, Vincent ;
Marcelin, Sabrina ;
Pebere, Nadine ;
Bunge, Annette L. ;
White, Erick A. ;
Riemer, Douglas P. ;
Musiani, Marco .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (06) :C215-C225
[25]   On the semi-infinite distributed resistor-constant phase element transmission line [J].
Allagui, Anis ;
Balaguera, Enrique H. .
ELECTROCHIMICA ACTA, 2025, 510
[26]   Electrochemical impedance spectroscopy study of thermally grown oxides exhibiting constant phase element behaviour [J].
Hamadou, L. ;
Ainouche, L. ;
Kadri, A. ;
Yahia, S. Ait Ali ;
Benbrahim, N. .
ELECTROCHIMICA ACTA, 2013, 113 :99-108
[27]   Contribution of Surface Distributions to Constant-Phase-Element (CPE) Behavior: 2. Capacitance [J].
Alexander, Christopher L. ;
Tribollet, Bernard ;
Orazem, Mark E. .
ELECTROCHIMICA ACTA, 2016, 188 :566-573
[28]   DEPENDENCY OF THE POWER OF THE CONSTANT PHASE ELEMENT TO OPERATING CONDITIONS IN PROTON EXCHANGE MEMBRANE FUEL CELLS [J].
Niya, Seyed Mohammad Rezaei ;
Phillips, Ryan ;
Hoorfar, Mina .
PROCEEDINGS OF THE ASME 13TH FUEL CELL SCIENCE, ENGINEERING, AND TECHNOLOGY CONFERENCE, 2015, 2016,
[29]   Electrochemical Impedance Spectroscopic Investigation of Sodium Ion Diffusion in MnO2 Using a Constant Phase Element Active in Desired Frequency Ranges [J].
Yoon, Seung-Beom ;
Jegal, Jong-Pil ;
Roh, Kwang Chul ;
Kim, Kwang-Bum .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (04) :H207-H213
[30]   Beyond Constant Current: Origin of Pulse-Induced Activation in Phase-Transforming Battery Electrodes [J].
Deng, Haitao D. ;
Jin, Norman ;
Attia, Peter M. ;
Lim, Kipil ;
Kang, Stephen D. ;
Kapate, Nidhi ;
Zhao, Hongbo ;
Li, Yiyang ;
Bazant, Martin Z. ;
Chueh, William C. .
ACS NANO, 2024, 18 (03) :2210-2218