The Origin of the Constant Phase Element

被引：132
作者：
Lasia, Andrzej
机构：
[1] Département de chimie, Université de Sherbrooke, Sherbrooke, J1K 2R1, QC
来源：
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2022年 / 13卷 / 02期
关键词：
ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ANION-ADSORPTION; CAPACITANCE DISPERSION; FREQUENCY DISPERSION; ELECTRODE; BEHAVIOR; DISTRIBUTIONS; INTERFACES; RESPONSES; KINETICS;
D O I：
10.1021/acs.jpclett.1c03782
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The constant phase element (CPE) is usually observed at solid electrodes. It is a source of controversies and misunderstandings. In this Viewpoint, theory, properties, experimental results, and the origin of the CPE are presented and discussed.
引用
收藏
页码：580 / 589
页数：10
相关论文
共 53 条
[1]   Influence of Micrometric-Scale Electrode Heterogeneity on Electrochemical Impedance Spectroscopy [J].
Alexander, Christopher L. ;
Tribollet, Bernard ;
Orazema, Mark E. .
ELECTROCHIMICA ACTA, 2016, 201 :374-379
[2]   Contribution of Surface Distributions to Constant-Phase-Element (CPE) Behavior: 2. Capacitance [J].
Alexander, Christopher L. ;
Tribollet, Bernard ;
Orazem, Mark E. .
ELECTROCHIMICA ACTA, 2016, 188 :566-573
[3]   HETEROGENEOUS ACID-BASE EQUILIBRIA AND REACTION ORDER OF OXYGEN EVOLUTION ON OXIDE ELECTRODES [J].
ANGELINETTA, C ;
FALCIOLA, M ;
TRASATTI, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 205 (1-2) :347-353
[4]   ELECTROCHEMICAL FACETING OF METAL-ELECTRODES [J].
ARVIA, AJ ;
CANULLO, JC ;
CUSTIDIANO, E ;
PERDRIEL, CL ;
TRIACA, WE .
ELECTROCHIMICA ACTA, 1986, 31 (11) :1359-1368
[5]  
Borisova T.I., 1950, Zh. Fiz. Khim., V24, P337
[6]   THE ANALYSIS OF ELECTRODE IMPEDANCES COMPLICATED BY THE PRESENCE OF A CONSTANT PHASE ELEMENT [J].
BRUG, GJ ;
VANDENEEDEN, ALG ;
SLUYTERSREHBACH, M ;
SLUYTERS, JH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 176 (1-2) :275-295
[7]   STUDY OF THE KINETICS OF HYDROGEN EVOLUTION REACTION ON NICKEL-ZINC ALLOY ELECTRODES [J].
CHEN, LL ;
LASIA, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (11) :3321-3328
[8]   Dispersion and absorption in dielectrics I. Alternating current characteristics [J].
Cole, KS ;
Cole, RH .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351
[9]   On the intrinsic coupling between constant-phase element parameters α and Q in electrochemical impedance spectroscopy [J].
Cordoba-Torres, P. ;
Mesquita, T. J. ;
Devos, O. ;
Tribollet, B. ;
Roche, V. ;
Nogueira, R. P. .
ELECTROCHIMICA ACTA, 2012, 72 :172-178
[10]   Relationship between the Origin of Constant-Phase Element Behavior in Electrochemical Impedance Spectroscopy and Electrode Surface Structure [J].
Cordoba-Torres, Pedro ;
Mesquita, Thiago J. ;
Nogueira, Ricardo P. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (08) :4136-4147
123456