Structural characterization and photocatalytic activity of B2O3/ZrO2-TiO2 mesoporous fibers

被引：37

作者：

Zhu, L. Y. ^{[1
,2
]}

Wang, X. Q. ^{[1
,2
]}

Zhang, G. H. ^{[1
,2
]}

Ren, Q. ^{[3
]}

Xu, D. ^{[1
,2
]}

机构：

[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[2] Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China

[3] Shandong Univ, Dept Opt, Jinan 250100, Peoples R China

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2011年 / 103卷 / 3-4期

基金：

中国博士后科学基金;

关键词：

B2O3/ZrO2-TiO2; Mesoporous fiber; Photocatalytic activity; Fiber paper; PHASE BECKMANN REARRANGEMENT; CYCLOHEXANONE OXIME; NONOXIDATIVE DEHYDROGENATION; TIO2-ZRO2; CATALYSTS; SURFACE-PROPERTIES; OXIDE CATALYSTS; TIO2; ETHYLBENZENE; B2O3/TIO2-ZRO2; SPECTROSCOPY;

D O I：

10.1016/j.apcatb.2011.02.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of B2O3/ZrO2-TiO2 mesoporous fibers using mixed precursor solutions were achieved without any templates by dry-spinning method with novel steam heat-treatment. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD). N-2 adsorption, UV-vis diffuse reflectance and Fourier transformation infrared (FTIR) spectroscopy. Although calcination at 800 degrees C, the mesoporous fibers exhibit higher surface area (similar to 80 m(2)/g) than pure ZrO2-TiO2 fibers and the only ZrTiO4 phase was observed. The pyridine adsorption on ZrO2-TiO2 sample indicates the presence of stronger surface acid sites. Such properties bring about that the mesoporous oxide system possesses higher efficiency and durable activity stability for photodegradation of methyl orange and phenol than P25 TiO2. In addition, the macroscopic paper form for the resulting materials is more beneficial for practical applications than traditional catalysts forms. (c) 2011 Elsevier B.V. All rights reserved.

引用

页码：428 / 435

页数：8

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