High resolution photo-absorption studies of acrylonitrile, C2H3CN, and acetonitrile, CH3CN

被引：33
作者：
Eden, S
Limao-Vieira, P
Kendall, P
Mason, NJ
Hoffmann, SV
Spyrou, SM
机构：
[1] UCL, Dept Phys & Astron, London WC1E 6BT, England
[2] Aarhus Univ, Inst Storage Rings, DK-8000 Aarhus C, Denmark
[3] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[4] Univ Nova Lisboa, FCT, Dept Fis, P-2829516 Caparica, Portugal
[5] IST, Ctr Fis Mol, P-1049001 Lisbon, Portugal
[6] Open Univ, Dept Phys & Astron, Ctr Mol & Opt Sci, Milton Keynes MK7 6AA, Bucks, England
来源：
EUROPEAN PHYSICAL JOURNAL D | 2003年 / 26卷 / 02期
关键词：
D O I：
10.1140/epjd/e2003-00223-5
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
High resolution photo-absorption spectra of acrylonitrile and acetonitrile have been recorded in the wavelength range 115 to 320 nm (10.8 to 3.9 eV). Results are compared with previous photo-absorption measurements and electron energy loss spectra and, in most cases, are found to be in close agreement. The high resolution achieved in the present work has allowed some structures to be observed for the first time and new assignments have been suggested accordingly. The role of the molecules in the terrestrial atmosphere is discussed.
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页码：201 / 210
页数：10
相关论文
共 30 条
[1]  
COSTAIN CC, 1965, J CHEM PHYS, V43, pS129
[2]   HIGH-RESOLUTION HE-I PHOTOELECTRON-SPECTRUM OF ACRYLONITRILE [J].
DELWICHE, J ;
GOCHELDUPUIS, M ;
COLLIN, JE ;
HEINESCH, J .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1993, 66 (1-2) :65-74
[3]   HIGH-RESOLUTION ABSORPTION CROSS-SECTION MEASUREMENTS OF SO2 AT 213-K IN THE WAVELENGTH REGION 172-240 NM [J].
FREEMAN, DE ;
YOSHINO, K ;
ESMOND, JR ;
PARKINSON, WH .
PLANETARY AND SPACE SCIENCE, 1984, 32 (09) :1125-1134
[4]   ELECTRONIC EXCITATION OF ACETONITRILE, METHYLISONITRILE AND PROPYNE [J].
FRIDH, C .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1978, 74 :2193-2203
[5]   ELECTRON-ENERGY LOSS SPECTROSCOPY OF THE OUTER VALENCE SHELLS OF ACETONITRILE AND METHYL ISOCYANIDE [J].
GOCHELDUPUIS, M ;
DELWICHE, J ;
HUBINFRANSKIN, MJ ;
COLLIN, JE ;
EDARD, F ;
TRONC, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5425-5431
[6]   A THEORETICAL-STUDY ON THE STRUCTURE OF ACETONITRILE (CH3CN) AND ITS ANION CH3CN- [J].
GUTSEV, GL ;
SOBOLEWSKI, AL ;
ADAMOWICZ, L .
CHEMICAL PHYSICS, 1995, 196 (1-2) :1-11
[7]   THE VIBRATIONAL SPECTRUM AND THERMODYNAMIC FUNCTIONS OF ACRYLONITRILE [J].
HALVERSON, F ;
STAMM, RF ;
WHALEN, JJ .
JOURNAL OF CHEMICAL PHYSICS, 1948, 16 (08) :808-816
[8]  
HEICKLEN J, 1976, ATMOSPHERE CHEM
[9]  
Herzberg G., 1966, MOL SPECTRA MOL STRU, V3
[10]   Biomass burning as a source of formaldehyde, acetaldehyde, methanol, acetone, acetonitrile, and hydrogen cyanide [J].
Holzinger, R ;
Warneke, C ;
Hansel, A ;
Jordan, A ;
Lindinger, W ;
Scharffe, DH ;
Schade, G ;
Crutzen, PJ .
GEOPHYSICAL RESEARCH LETTERS, 1999, 26 (08) :1161-1164
123