Hypervalent iodine compounds derived from o-nitroiodobenzene and related compounds: syntheses and structures

被引：42
作者：
Nikiforov, VA [1 ]
Karavan, VS
Miltsov, SA
Selivanov, SI
Kolehmainen, E
Wegelius, E
Nissinen, M
机构：
[1] St Petersburg State Univ, Inst Chem, Univ Pr 2, St Petersburg 198904, Russia
[2] Univ Jyvaskyla, Dept Chem, FIN-40014 Jyvaskyla, Finland
来源：
ARKIVOC | 2003年
关键词：
o-nitroiodobenzene; hypervalent iodine compounds; 1,2-benziodox-3-azolin-3-onium ion;
D O I：
10.3998/ark.5550190.0004.621
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of compounds possessing polyvalent iodine groups was prepared from o-nitroiodobenzene. Single crystal X-ray investigation revealed a strong interaction between iodine atom and one of the oxygen atoms of the nitro group. This interaction is strongest in trifluoroacetate of hydroxy(o-nitrophenyl) iodonium salt, which is formed from an iodosylarene and an acid being the first example of this new class of compounds. These compounds are also characterized by NMR-spectroscopy.
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页码：191 / 200
页数：10
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