Preparation of polystyrene-supported soluble palladacycle catalyst for Heck and Suzuki reactions

被引：33
作者：
Luo, FT [1 ]
Xue, CH
Ko, SL
Shao, YD
Wu, CJ
Kuo, YM
机构：
[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[2] Sichuan Univ, Fac Chem, Chengdu 610064, Peoples R China
[3] Chinese Culture Univ, Inst Appl Chem, Taipei 111, Taiwan
来源：
TETRAHEDRON | 2005年 / 61卷 / 25期
关键词：
supported catalyst; Heck reaction; Suzuki reaction; recyclable catalyst; polystyrene-bound catalyst; palladacycle catalyst;
D O I：
10.1016/j.tet.2005.04.036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A polystyrene-supported palladium complex soluble in tetrahydrofuran and N,N-dimethylacetamide and precipitated in diethyl ether or acetonitrile was prepared from two routes as an excellent and recyclable palladacycle catalyst for carbon-carbon bond formation in Heck and Suzuki reactions to give high yields of the desired products. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6040 / 6045
页数：6
相关论文
共 37 条
[1]   Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction [J].
Albisson, DA ;
Bedford, RB ;
Scully, PN .
TETRAHEDRON LETTERS, 1998, 39 (52) :9793-9796
[2]   Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions [J].
Albisson, DA ;
Bedford, RB ;
Lawrence, SE ;
Scully, PN .
CHEMICAL COMMUNICATIONS, 1998, (19) :2095-2096
[3]   First efficient palladium-catalyzed Heck reactions of aryl bromides with alkyl methacrylate [J].
Beller, M ;
Riermeier, TH .
TETRAHEDRON LETTERS, 1996, 37 (36) :6535-6538
[4]   PALLADACYCLES AS EFFICIENT CATALYSTS FOR ARYL COUPLING REACTIONS [J].
BELLER, M ;
FISCHER, H ;
HERRMANN, WA ;
OFELE, K ;
BROSSMER, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1848-1849
[5]   Hydrogenation of organic substrates by an heterogenized catalyst based on a bis(diphenylphosphino)methane polymer-bound palladium(II) complex [J].
Benvenuti, F ;
Carlini, C ;
Marchionna, M ;
Galletti, AMR ;
Sbrana, G .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 145 (1-2) :221-228
[6]  
Bergbreiter D E, 2001, Curr Opin Drug Discov Devel, V4, P736
[7]   Palladium-catalyzed C-C coupling under thermomorphic conditions [J].
Bergbreiter, DE ;
Osburn, PL ;
Wilson, A ;
Sink, EM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) :9058-9064
[8]   Tridentate SCS palladium(II) complexes: New, highly stable, recyclable catalysts for the heck reaction [J].
Bergbreiter, DE ;
Osburn, PL ;
Liu, YS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9531-9538
[9]   The use of soluble polymers to effect homogeneous catalyst separation and reuse [J].
Bergbreiter, DE .
CATALYSIS TODAY, 1998, 42 (04) :389-397
[10]   Thermomorphic rhodium(I) and palladium(0) catalysts [J].
Bergbreiter, DE ;
Liu, YS ;
Osburn, PL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (17) :4250-4251
1234