Transition metals supported on activated carbon as benzene hydroxylation catalysts

被引：27

作者：

Choi, JS

Kim, TH

Choo, KY

Sung, JS

Saidutta, MB

Song, SD

Rhee, YW ^{[1
]}

机构：

[1] Chungnam Natl Univ, Dept Chem Engn, Taejon, South Korea

[2] KIER, Taejon, South Korea

[3] Natl Inst Technol Karnataka, Dept Chem Engn, Mangalore 575025, India

[4] Hanseo Univ, Dept Phys, Chungnam, South Korea

来源：

JOURNAL OF POROUS MATERIALS | 2005年 / 12卷 / 04期

关键词：

activated carbon; transition metals; hydroxylation of benzene; phenol;

D O I：

10.1007/s10934-005-3128-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The direct conversion of benzene to phenol by hydroxylation with hydrogen peroxide was carried out over catalyst containing various transition metals impregnated on activated carbon. Iron and vanadium impregnated catalysts gave better yields of phenol compared to copper impregnated catalysts. The activity of transition metals supported on activated carbon catalyst in the production of phenol was V > Fe > Cu. In addition to the role of transition metals in catalyzing the hydroxylation reaction, the hydrophobic nature of the activated carbon surface and also the surface acidity and basicity seems to have enhanced the performance of these catalysts.

引用

页码：301 / 310

页数：10

共 24 条

[1] Triphase catalysis over titanium-silicate molecular sieves under solvent-free conditions - I. Direct hydroxylation of benzene [J].