XPS and FTIR investigation of the surface properties of different prepared titania nano-powders

被引：279
作者：
Jensen, H
Soloviev, A
Li, ZS
Sogaard, EG
机构：
[1] Aalborg Univ, Dept Chem Engn, DK-6700 Esbjerg, Denmark
[2] Aarhus Univ, Inst Storage Ring Facil, DK-8000 Aarhus, Denmark
来源：
APPLIED SURFACE SCIENCE | 2005年 / 246卷 / 1-3期
关键词：
TiO2; surface hydroxyl groups; preparation methods; XPS; FTIR;
D O I：
10.1016/j.apsusc.2004.11.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Surface studies of nano-sized TiO2 powders prepared by different methods showed that the preparation method had great impact on the surface properties. XPS measurements showed that the oxygen composition was related to the preparation method. The chloride method yielded the lowest amount of surface oxygen (29%) and sol-gel prepared powder showed the greatest amount of surface oxygen (66%) in the form of surface hydroxyl groups. The remaining oxygen was identified as lattice oxygen. The powder prepared by the sol-gel method contained carbon impurities originating from residual alkoxy groups. Supercritical sol-gel prepared powder and powder prepared by the sulphate method revealed same trends regarding oxygen composition with 44-47% being surface oxygen; neither contained carbon impurities. The results obtained from XPS were confirmed by FTIR measurements. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：239 / 249
页数：11
相关论文
共 31 条
[1]  
Brinker C.J., 1990, SOL GEL SCI
[2]   Anatase-TiO2 nano-particle preparation with a micro-mixing technique and its photocatalytic performance [J].
Chen, GG ;
Luo, GS ;
Yang, XR ;
Sun, YW ;
Wang, JD .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 380 (1-2) :320-325
[3]   Structural influence on charge-carrier lifetimes in TiO2 powders studied by microwave absorption [J].
Colbeau-Justin, C ;
Kunst, M ;
Huguenin, D .
JOURNAL OF MATERIALS SCIENCE, 2003, 38 (11) :2429-2437
[4]   FTIR spectroscopy, SAXS and electrical conductivity studies of the hydrolysis and condensation of zirconium and titanium alkoxides [J].
Harris, MT ;
Singhal, A ;
Look, JL ;
SmithKristensen, JR ;
Lin, JS ;
Toth, LM .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1997, 8 (1-3) :41-47
[5]   Formation and investigation of sol-gel TiO2-V2O5 system [J].
Ivanova, T ;
Harizanova, A ;
Surtchev, M .
MATERIALS LETTERS, 2002, 55 (05) :327-333
[6]   Effect of particle size and phase composition of titanium dioxide nanoparticles on the photocatalytic properties [J].
Jang, HD ;
Kim, SK ;
Kim, SJ .
JOURNAL OF NANOPARTICLE RESEARCH, 2001, 3 (2-3) :141-147
[7]  
JENSEN H, 2003, Patent No. 2004001278
[8]  
JENSEN H, IN PRESS J NANOPART
[9]  
JENSEN H, UNPUB
[10]   The surface properties and photocatalytic activities of ZnO ultrafine particles [J].
Jing, LQ ;
Xu, ZL ;
Sun, XJ ;
Shang, J ;
Cai, WM .
APPLIED SURFACE SCIENCE, 2001, 180 (3-4) :308-314
1234