Synthesis of environment friendly nonionic surfactants from sugar base and characterization of interfacial properties for detergent application

被引:63
作者
Lee, SuMin [1 ]
Lee, JuYeon [1 ]
Yu, HyonPil [2 ]
Lim, JongChoo [1 ]
机构
[1] Dongguk Univ Seoul, Dept Chem & Biochem Engn, Seoul 100715, South Korea
[2] AK ChemTech Cent Res Lab, DaeJeon, South Korea
关键词
Environment friendly; Nonionic surfactant; Interfacial property; Detergent; CATIONIC SURFACTANTS; ACTIVE PROPERTIES; AMMONIUM; BIOCOMPATIBILITY; EMULSIFICATION; BIODEGRADATION;
D O I
10.1016/j.jiec.2016.04.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, environment friendly nonionic surfactants were synthesized from sugar base and their structure was characterized by H-1-NMR, C-13-NMR and FT-IR. The newly synthesized SA08 series surfactants showed excellent interfacial properties such as low CMC, surface tension and interfacial tension, and superior foam stability. Detergency tests using three different types of artificial soils have revealed that the synthesized surfactants showed moderately good detergency presumably due to excellent interfacial properties and stereoscopic molecular structure of SA08 series surfactants. Environmental compatibility test showed that SA08-07 surfactant exhibited low toxicity compared with conventional nonionic and anionic surfactants and excellent biodegradability. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:157 / 166
页数:10
相关论文
共 35 条
[1]  
Bikerman JJ., 1973, Foams, DOI 10.1007/978-3-642-86734-7
[2]   The biodegradation of monomeric and dimeric alkylammonium surfactants [J].
Brycki, Bogumil ;
Waligorska, Malgorzata ;
Szulc, Adrianna .
JOURNAL OF HAZARDOUS MATERIALS, 2014, 280 :797-815
[3]   Levels and trends of poly- and perfluorinated compounds in the arctic environment [J].
Butt, Craig M. ;
Berger, Urs ;
Bossi, Rossana ;
Tomy, Gregg T. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2010, 408 (15) :2936-2965
[4]   Study on the effect of structure of polydimethylsiloxane grafted with polyethyleneoxide on surface activities [J].
Chung, Dae-Won ;
Lim, Jong Choo .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 336 (1-3) :35-40
[5]   Environment-friendly ester bonded gemini surfactant: Mixed micellization of 14-E2-14 with ionic and nonionic conventional surfactants [J].
Fatma, Nazish ;
Panda, Manorama ;
Ansari, Wajid Husain ;
Kabir-ud-Din .
JOURNAL OF MOLECULAR LIQUIDS, 2015, 211 :247-255
[6]   Mass spectrometry as an indispensable tool for studies of biodegradation of surfactants [J].
Froemel, Tobias ;
Knepper, Thomas P. .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2008, 27 (11) :1091-1106
[7]   Development and application of kinetic models for the primary biodegradation of non-ionic surfactants [J].
Jurado, E. ;
Fernandez-Serrano, M. ;
Camacho, F. ;
Nunez Olea, J. ;
Lechuga, M. ;
Luzon, G. .
CHEMICAL ENGINEERING JOURNAL, 2009, 150 (2-3) :440-446
[8]   A novel cationic surfactant having two quaternary ammonium ions [J].
Kang, Eun-kyung ;
Lee, Byung Min ;
Hwang, Hyun Ah ;
Lim, Jong Choo .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2011, 17 (5-6) :845-852
[9]  
KSM K. S., 2007, 2714 TEST METH BIOD
[10]  
Lee Byung Min, 2012, [Applied Chemistry for Engineering, 공업화학], V23, P433