Luminescence spectra of Ho3+ in distorted parity-breaking HoF63- octahedra

被引:10
作者
Aleksandrovsky, A. S. [1 ,2 ]
Krylov, A. S. [1 ]
Malakhovskii, A. V. [1 ]
Voronov, V. N. [1 ]
机构
[1] LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
[2] Siberian Fed Univ, Krasnoyarsk, Russia
基金
俄罗斯基础研究基金会;
关键词
Luminescence; Holmium; Distorted octahedra; Monoclinic crystals;
D O I
10.1016/j.jlumin.2011.11.005
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Low temperature luminescence spectrum of holmium ions in monoclinic Rb2KHoF6 crystal was found to be well analyzable by the comparison with earlier studied cubic Cs2NaHoF6. The manifestation of the local symmetry influence on the strength of individual lines is found to be distinctive. In the absence of structural data, the local symmetry of holmium in Rb2KHoF6 is proved to be a non-centrosymmetric one. The concentration quenching of holmium luminescence in Rb2KHoF6 is found to be rather modest. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:690 / 692
页数:3
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