Synthesis of sulfoximine-derived P,N ligands and their applications in asymmetric quinoline hydrogenations

被引：104

作者：

Lu, Sheng-Mei ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 7-8期

关键词：

asymmetric catalysis; enantioselectivity; hydrogenation; iridium; quinolines; sulfoximines;

D O I：

10.1002/adsc.200800068

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of naphthalene-bridged P,N-type sulfoximine ligands and their iridium complexes have been synthesized. They were applied in the enantioselective hydrogenation of quinoline derivatives, and enantioselectivities up to 92% ee have been achieved in the hydrogenation of 2-methylquinoline.

引用

页码：1101 / 1105

页数：5

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