Effect of carbon black content on electrical and microwave absorbing properties of polyaniline/carbon black nanocomposites

被引：142

作者：

Wu, K. H. ^{[1
]}

Ting, T. H. ^{[1
]}

Wang, G. P. ^{[2
]}

Ho, W. D. ^{[2
]}

Shih, C. C. ^{[2
]}

机构：

[1] Natl Def Univ, Chung Cheng Inst Technol, Dept Appl Chem & Mat Sci, Tao Yuan, Taiwan

[2] Chung Shan Inst Sci & Technol, Chem Syst Res Div, Tao Yuan, Taiwan

来源：

POLYMER DEGRADATION AND STABILITY | 2008年 / 93卷 / 02期

关键词：

carbon black; polyaniline; reflection loss; microwave absorber;

D O I：

10.1016/j.polymdegradstab.2007.11.009

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Carbon black coated with polyaniline, forming a core-shell structure, was synthesized by in situ polymerization at different carbon black contents (5-30 wt.%) and introduced into epoxy resin to be a microwave absorber. The spectroscopic characterizations of the formation processes of polyaniline/carbon black composites were studied using Fourier transform infrared, ultraviolet-visible spectrophotometer, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and electron spin resonance. Microwave absorbing properties were investigated by measuring reflection loss in the 2-18 and 18-40 GHz microwave frequencies range using the free space method. The results showed that a wider absorption frequency range could be obtained by adding different carbon black contents in polyaniline. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：483 / 488

页数：6

共 26 条

[1] Graphite/Polyaniline (GP) composites: Synthesis and characterization [J].

Bourdo, SE ;

Viswanathan, T .

CARBON, 2005, 43 (14) :2983-2988

[2] Electron spin resonance:: A major probe for molecular conductors [J].

Coulon, C ;

Clérac, R .

CHEMICAL REVIEWS, 2004, 104 (11) :5655-5687

[3] Electrically conductive carbon black (CB) filled in situ microfibrillar poly(ethylene terephthalate) (PET)/polyethylene (PE) composite with a selective CB distribution [J].

Dai, Kun ;

Xu, Xiang-Bin ;

Li, Zhong-Ming .

POLYMER, 2007, 48 (03) :849-859

[4] Novel flexible, freestanding and transparent organic/inorganic hybrid materials formed between polyaniline and polyphosphate gel [J].

de Castro, EG ;

Zarbin, AJG ;

de Oliveira, HP ;

Galembeck, A .

SYNTHETIC METALS, 2004, 146 (01) :57-62

[5] Electromagnetic shielding behaviour of conducting polyaniline composites [J].

Dhawan, S. K. ;

Singh, N. ;

Rodrigues, D. .

SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2003, 4 (02) :105-113

[6] Synthesis of polyaniline/graphite composite as a cathode of Zn-polyaniline rechargeable battery [J].

Ghanbari, Khadijeh ;

Mousavi, Mir Fazlollah ;

Sharnsipur, Mojtaba ;

Karami, Hassan .

JOURNAL OF POWER SOURCES, 2007, 170 (02) :513-519

[7] A FREE-SPACE METHOD FOR MEASUREMENT OF DIELECTRIC-CONSTANTS AND LOSS TANGENTS AT MICROWAVE-FREQUENCIES [J].

GHODGAONKAR, DK ;

VARADAN, VV ;

VARADAN, VK .

IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, 1989, 38 (03) :789-793

[8] Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries [J].

Jugovic, B. Z. ;

Trisovic, T. Lj. ;

Stevanovic, J. S. ;

Maksimovic, M. D. ;

Grgur, B. N. .

ELECTROCHIMICA ACTA, 2006, 51 (28) :6268-6274

[9]

Kan JQ, 2002, B ELECTROCHEM, V18, P477

[10] New dry and wet Zn-polyaniline bipolar batteries and prediction of voltage and capacity by ANN [J].

Karami, H ;

Mousavi, MF ;

Sharnsipur, M ;

Riahi, S .

JOURNAL OF POWER SOURCES, 2006, 154 (01) :298-307

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