Efficient and green one-pot synthesis of Knoevenagel condensation catalyzed nano metal-organic frameworks in water

被引：4
作者：
Mansouri, Ghobad [1 ]
Abdizad, Mino [2 ]
Abbasi, Amir Reza [2 ]
Rezayati, Sobhan [1 ]
机构：
[1] Payame Noor Univ PNU, Dept Chem, POB 19395-4697, Tehran, Iran
[2] Razi Univ, Fac Chem, Kermanshah, Iran
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2022年 / 36卷 / 12期
关键词：
EtA-NH-66-UiO; Knoevenagel condensation; metal-organic framework; Mlam-NH-66-UiO; MOF catalysis; AROMATIC-ALDEHYDES; UIO-66-NH2; CO2; STABILIZATION; NANOPARTICLES; REMOVAL; OXIDE; MOF;
D O I：
10.1002/aoc.6866
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Metal-organic frameworks (MOFs), Mlam-NH-66-UiO and EtA-NH-66-UiO, were prepared via post-synthesis of the H2N-66-UiO and used as an efficient heterogeneous catalyst for Knoevenagel condensation of various aldehydes with malononitrile in water. The modified MOFs exhibited excellent catalyst activities in heterogeneous phase because of their large pore sizes and surface area, porosity, and the number of catalytically active sites (-NH2) on structures. In addition, the catalysts can be recycled and reused without decomposition of MOF structure and losing catalytic activity.
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页数：17
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