Ruthenium Porphyrin Catalyzed Synthesis of Oxazolidin-2-ones by Cycloaddition of CO2 to Aziridines

被引：27

作者：

Carminati, Daniela ^{[1
]}

Gallo, Emma ^{[2
]}

Damiano, Caterina ^{[2
]}

Caselli, Alessandro ^{[2
]}

Intrieri, Daniela ^{[2
]}

机构：

[1] Univ Rochester, Dept Chem, 416 Hutchison Hall, Rochester, NY USA

[2] Univ Milan, Dept Chem, Via Golgi 19, I-20133 Milan, Italy

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 48期

关键词：

Carbon dioxide fixation; Cycloaddition; Homogeneous catalysis; Porphyrinoids; Ruthenium; CARBON-DIOXIDE; EPOXIDES; OXAZOLIDINONES; AMINATION; FIXATION; MILD; DFT;

D O I：

10.1002/ejic.201801208

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between N-substituted-2-arylaziridines and CO2 is efficiently promoted by ruthenium(VI) imidoporphyrin complexes and yields a mixture of 5-aryl (A) and 4-aryl (B) substituted oxazolidin-2-ones with a regioisomeric A/B ratio up to 99:1. Several oxazolidin-2-one molecules were synthesized at 100 degrees C and 0.6 MPa of carbon dioxide by using the low catalytic loading of 1 mol-%. The formation of a deactivated compound, deriving from the ruthenium catalyst, suggested a possible catalytic role of imido nitrogen atoms.

引用

页码：5258 / 5262

页数：5

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