3-D pillared clay mimics of lanthanide-organic frameworks constructed from 5-fluoroisophthalic acid and 4,4′-bipyridine through hydrogen bonds

被引:7
|
作者
Zhang, Zhi-Hui [1 ]
Chen, Sheng-Chun [1 ]
Mi, Jin-Ling [1 ]
He, Ming-Yang [1 ]
Chen, Qun [1 ]
Wu, Zeng-Hui [1 ]
Hu, Zhao-Jian [1 ]
机构
[1] Changzhou Univ, Key Lab Fine Petrochem Technol, Changzhou 213164, Peoples R China
关键词
Lanthanide-organic frameworks; 2-D layered network; Clay mimics; Luminescence; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESES; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; GUEST INCLUSION; 2-D; INTERCALATION; CARBOXYLATES; COMPLEXES; COMPOUND;
D O I
10.1016/j.inoche.2010.08.010
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Four 2-D lanthanide coordination polymers constructed from 5-fluoroisophthalic acid show reliable 3-D pillared clay mimics based on the secondary hydrogen-bonding with 4,4'-bipyridine templates. The dimensionality of the structures turns out to be independent of the ionic radius of the lanthanide centers and the Eu-II; complex displays strong red luminescence. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1435 / 1438
页数:4
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