Composition and thermodynamic properties of thermal plasma with condensed phases

被引：34
作者：
Coufal, O. [1 ]
Zivny, O. [2 ]
机构：
[1] Brno Univ Technol, Fac Elect Engn & Commun, Brno 61600, Czech Republic
[2] Brno Univ Technol, Fac Chem, Brno 61200, Czech Republic
来源：
EUROPEAN PHYSICAL JOURNAL D | 2011年 / 61卷 / 01期
关键词：
EQUILIBRIUM COMPOSITION; CHEMICAL-EQUILIBRIUM; PARTITION-FUNCTIONS;
D O I：
10.1140/epjd/e2010-10211-3
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The initial relations of a method for calculating the composition and thermodynamic properties of a closed heterogeneous system in thermodynamic equilibrium at constant pressure and temperature are given. The gaseous phase is always present in the system, and substances in the condensed state can also be present, which are divided into several condensed phases. The essence of the method consists in the minimizing the Gibbs energy of a system in ideal state. The application possibilities of the method described are discussed in detail. The main aim of the article is to provide solutions to problems arising in the calculations of composition and thermodynamic properties. These problems are not only of physico-chemical nature but they also relate to the numerical calculations and stability. The nature of the problems is general and independent of computation method.
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页码：131 / 151
页数：21
相关论文
共 63 条
  • [1] Alemasov V. E., 1971, TERMODINAMICHESKIE T, V1
  • [2] [Anonymous], 1964, PHYS CHEM
  • [3] [Anonymous], 1998, NIST JANAF THERMOC 1
  • [4] APPEN WD, 1987, ASTROPHYS J, V319, P195
  • [5] Atkins P. W., 1978, Physical Chemistry
  • [6] Radiative emission from air thermal plasmas with vapour of Cu or W
    Aubrecht, V.
    Bartlova, M.
    Coufal, O.
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (43)
  • [7] Aubrecht V, 2002, P 15 INT C GAS DISCH, V1, P47
  • [8] AUBRECHT V, 2001, 14 S PHYS SWITCH ARC, P12
  • [9] BARTLOVA M, 1987, INT C PHEN ION GAS S, V1, P170
  • [10] Birkhoff G., 1965, A Survey of Modern Algebra, Vthird
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