Separation and recovery of gold(III) from base metal ions using melamine-formaldehyde-thiourea chelating resin

被引：71

作者：

Aydin, Abduelhakim ^{[1
]}

Imamoglu, Mustafa ^{[1
]}

Gulfen, Mustafa ^{[1
]}

机构：

[1] Sakarya Univ, Dept Chem, Fac Arts & Sci, Sakarya, Turkey

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2008年 / 107卷 / 02期

关键词：

melamin-formaldehyde-thiourea resin; chelating resin; gold(III); adsorption; elution;

D O I：

10.1002/app.27178

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Melamine-formaldehyde-thiourea (MFT) chelating resin has been prepared. An 31 ions uptake behavior and selectivity of the chelating resin were investigated by both batch and column methods. MFT resin showed higher affinity toward Au3+ compared with base metal ions, CU2+ and Zn2+. The highest Au3+ uptake values were obtained at pH 2 and Au3+ adsorption capacity of the resin was calculated as 48 mg Au3+/g resin (0.246 mmol Au3+/g resin) by batch method. it was concluded that Au3+ ions could be selectively concentrated from the solution including Cu2+ and Zn2+ base metal ions by column method. (C) 2007 Wiley Periodicals, Inc.

引用

页码：1201 / 1206

页数：6

共 38 条

[1] Processing of residual gold (III) solutions via ion exchange [J].

Alguacil, FJ ;

Adeva, P ;

Alonso, M .

GOLD BULLETIN, 2005, 38 (01) :9-13

[2]

[Anonymous], LANGES HDB CHEM

[3] Gold sorption on chitosan derivatives [J].

Arrascue, ML ;

Garcia, HM ;

Horna, O ;

Guibal, E .

HYDROMETALLURGY, 2003, 71 (1-2) :191-200

[4] Adsorption of silver(I) and gold(III) on resins derived from bisthiourea and application to retrieval of silver ions from processed photo films [J].

Atia, AA .

HYDROMETALLURGY, 2005, 80 (1-2) :98-106

[5] Comparative study of the recovery of silver(I) from aqueous solutions with different chelating resins derived from glycidyl methacrylate [J].

Atia, AA ;

Donia, AM ;

Yousif, AM .

JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 97 (03) :806-812

[6]

Bartkowiak D. J., 2002, EUR POLYM J, V38, P2239

[7]

Bilba D, 1998, CROAT CHEM ACTA, V71, P155

[8] Solid phase extraction of trace elements [J].

Camel, V .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2003, 58 (07) :1177-1233

[9] Recovery of gold(III) ions by a chitosan-coated magnetic nano-adsorbent [J].

Chang, Yang-Chuang ;

Chen, Dong-Hwang .

GOLD BULLETIN, 2006, 39 (03) :98-102

[10] Synthesis and characterization of polyacrylonitrile-thiosemicarbazide resin and its sorption behavior for Rh(III) Ru(IV) Pd(II) and Ir(IV) ions [J].

Chen, YY ;

Liang, C ;

Chao, Y .

REACTIVE & FUNCTIONAL POLYMERS, 1998, 36 (01) :51-58

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