H5[PMo10V2O40] as a Green, Reusable, and Highly Efficient Catalyst for the Oxidation of Dithiols in Intermolecular Reactions Using Permanganate as an Oxidizing Reagent

被引：29

作者：

Harutyunyan, R. ^{[1
]}

Rezvani, M. A. ^{[2
]}

Heravi, Majid M. ^{[3
]}

机构：

[1] Yerevan State Univ, Dept Chem, Yerevan 0025, Armenia

[2] Univ Guilan, Fac Sci, Dept Chem, Rasht, Iran

[3] Alzahra Univ, Dept Chem, Sch Sci, Tehran, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 01期

关键词：

Dawson structure; disulfides; dithiols; heteropolyacids; hydrogen peroxide; Keggin; polyoxoanions; HETEROPOLY-COMPOUNDS; ACIDS; THIOLS; CSXH3-XPW12O40; DISULFIDES; CHEMISTRY; MILD;

D O I：

10.1080/15533174.2010.538019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[H5PV2Mo10O40] catalyzed oxidation of dithiols to related cyclic disulfides. Potassium permanganate as an oxidizing reagent under mild conditions was carried out in this reaction. This system provides an efficient, convenient, and practical method for the syntheses of cyclic disulfides. In this work, the comparisons among the Keggin and Dawson ions are addressed in term of relative stability hardness and acidity.

引用

页码：94 / 99

页数：6

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