Microwave-assisted synthesis: A fast and efficient route to produce LaMO3 (M = Al, Cr, Mn, Fe, Co) perovskite materials

被引：55
作者：
Prado-Gonjal, J. [1 ]
Arevalo-Lopez, A. M. [1 ]
Moran, E. [1 ]
机构：
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, E-28040 Madrid, Spain
来源：
MATERIALS RESEARCH BULLETIN | 2011年 / 46卷 / 02期
关键词：
Oxides; Inorganic compounds; Chemical synthesis; Magnetic properties; X-ray diffraction; Thermogravimetric analysis; Crystal structure; HYDROTHERMAL SYNTHESIS; OXYGEN STOICHIOMETRY; RAPID SYNTHESIS; LAFEO3; OXIDES; CATHODE;
D O I：
10.1016/j.materresbull.2010.11.010
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of lanthanum perovskites, LaMO3 (M = Al, Cr, Mn, Fe, Co), having important technological applications, have been successfully prepared by a very fast, inexpensive, reproducible, environment-friendly method: the microwave irradiation of the corresponding mixtures of nitrates. Worth to note, the microwave source is a domestic microwave oven. In some cases the reaction takes place in a single step, while sometimes further annealings are necessary. For doped materials the method has to be combined with others such as sol-gel. Usually, nanopowders are produced which yield high density pellets after sintering. Rietveld analysis, oxygen stoichiometry, microstructure and magnetic measurements are presented. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：222 / 230
页数：9
相关论文
共 48 条
  • [1] Multiferroic behavior of lanthanum orthoferrite (LaFeO3)
    Acharya, S.
    Mondal, J.
    Ghosh, S.
    Roy, S. K.
    Chakrabarti, P. K.
    [J]. MATERIALS LETTERS, 2010, 64 (03) : 415 - 418
  • [2] Crystal structure and microdomain texture in RuSr2HoCu2O8
    Aguirre, MH
    Ruiz-Bustos, R
    Alario-Franco, MA
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (05) : 1156 - 1160
  • [3] Structuration of LaMnO3 perovskite catalysts on ceramic and metallic monoliths:: Physico-chemical characterisation and catalytic activity in methane combustion
    Arendt, E.
    Maione, A.
    Klisinska, A.
    Sanz, O.
    Montes, M.
    Suarez, S.
    Blanco, J.
    Ruiz, P.
    [J]. APPLIED CATALYSIS A-GENERAL, 2008, 339 (01) : 1 - 14
  • [4] SOFC - A playground for solid state chemistry
    Backhaus-Ricoult, Monika
    [J]. SOLID STATE SCIENCES, 2008, 10 (06) : 670 - 688
  • [5] MICROWAVE SYNTHESES FOR SUPERCONDUCTING CERAMICS
    BAGHURST, DR
    CHIPPINDALE, AM
    MINGOS, DMP
    [J]. NATURE, 1988, 332 (6162) : 311 - 311
  • [6] APPLICATION OF MICROWAVE-HEATING TECHNIQUES FOR THE SYNTHESIS OF SOLID-STATE INORGANIC-COMPOUNDS
    BAGHURST, DR
    MINGOS, DMP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (12) : 829 - 830
  • [7] Morphology-controlled growth of ZnO nanostructures using microwave irradiation: from basic to complex structures
    Cho, Seungho
    Jung, Seung-Ho
    Lee, Kun-Hong
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (33) : 12769 - 12776
  • [8] Oxygen reduction on LaMnO3-based cathode materials in solid oxide fuel cells
    Choi, YongMan
    Mebane, David S.
    Lin, M. C.
    Liu, Meilin
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (07) : 1690 - 1699
  • [9] Clark D.E., 2005, MICROWAVE SOLUTIONS
  • [10] THE EFFECT OF OXYGEN STOICHIOMETRY ON PHASE-RELATIONS AND STRUCTURE IN THE SYSTEM LA1-XSRXFEO3-DELTA (0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-1, 0-LESS-THAN-OR-EQUAL-TO-DELTA-LESS-THAN-OR-EQUAL-TO-0.5)
    DANN, SE
    CURRIE, DB
    WELLER, MT
    THOMAS, MF
    ALRAWWAS, AD
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1994, 109 (01) : 134 - 144
12345